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Thermal decomposition of cadmium peroxotitanate to CdTiO 3

Thermal decomposition of cadmium peroxotitanate to CdTiO 3 TG, DTA and DSC curves of Cd 2 (Ti 2 (O 2 ) 2 O(OH) 6 )·H 2 O were recorded and used to determine the isothermal conditions suitable for obtaining the intermediate samples corresponding to the phases observed during the thermal decomposition. The samples were identified by quantitative analysis, IR spectroscopy and X-ray analysis. The experimental results were used to propose a mechanism of thermal decomposition of the investigated compound to CdTiO 3 . The optimum conditions were also determined for obtaining CdTiO 3 with well-defined crystallinity. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Thermal Analysis and Calorimetry Springer Journals

Thermal decomposition of cadmium peroxotitanate to CdTiO 3

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References (8)

Publisher
Springer Journals
Copyright
Copyright © 2006 by Springer-Verlag
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry; Polymer Sciences; Measurement Science, Instrumentation
ISSN
1388-6150
eISSN
1572-8943
DOI
10.1007/s10973-005-7022-z
Publisher site
See Article on Publisher Site

Abstract

TG, DTA and DSC curves of Cd 2 (Ti 2 (O 2 ) 2 O(OH) 6 )·H 2 O were recorded and used to determine the isothermal conditions suitable for obtaining the intermediate samples corresponding to the phases observed during the thermal decomposition. The samples were identified by quantitative analysis, IR spectroscopy and X-ray analysis. The experimental results were used to propose a mechanism of thermal decomposition of the investigated compound to CdTiO 3 . The optimum conditions were also determined for obtaining CdTiO 3 with well-defined crystallinity.

Journal

Journal of Thermal Analysis and CalorimetrySpringer Journals

Published: May 1, 2006

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