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Abstract The oxidation of zirconium by supercritical CO2 (20.2 and 14.1 MPa, and 823 K) results in the formation of a layer of the monoclinic ZrO2 and amorphous carbon. In the constant electric field (E = 293 kV/m) when a sample of zirconium is the anode, the formation of amorphous carbon leads to a growth of leakage current and a twelve-fold increase in the rate of zirconium oxidation.
Thermophysics and Aeromechanics – Springer Journals
Published: Jul 1, 2016
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