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K. Rangan, P. Trikalitis, M. Kanatzidis (2000)
Light-Emitting Meso-Structured Sulfides with Hexagonal Symmetry: Supramolecular Assembly of [Ge4S10]4- Clusters with Trivalent Metal Ions and Cetylpyridinium SurfactantJournal of the American Chemical Society, 122
P. Trikalitis, K. Rangan, T. Bakas, M. Kanatzidis (2001)
Varied pore organization in mesostructured semiconductors based on the [SnSe4]4- anionNature, 410
P. Trikalitis, K. Rangan, T. Bakas, M. Kanatzidis (2002)
Single-crystal mesostructured semiconductors with cubic Ia3d symmetry and ion-exchange properties.Journal of the American Chemical Society, 124 41
Ulrike Ciesla, S. Schacht, G. Stucky, K. Unger, F. Schüth (1996)
Formation of a Porous Zirconium Oxo Phosphate with a High Surface Area by a Surfactant‐Assisted SynthesisAngewandte Chemie, 35
M. Wong, J. Ying (1998)
Amphiphilic Templating of Mesostructured Zirconium OxideChemistry of Materials, 10
Jing Li, Yolanda Liszewski, Leonard MacAdams, Feng Chen, S. Mulley, D. Proserpio (1996)
Synthesis and characterization of Ba2SnTe5 : A new zintl phase containing unique one-dimensional chains of (SnTe3)2- and dimeric units of (Te2)2-Chemistry of Materials, 8
Terry Nassivera, A. Eklund, C. Landry (2002)
Size-exclusion chromatography of low-molecular-mass polymers using mesoporous silica.Journal of chromatography. A, 973 1-2
P. Yang, Dongyuan Zhao, D. Margolese, B. Chmelka, G. Stucky (1998)
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworksNature, 396
J. Huffman, J. Haushalter, A. Umarji, G. Shenoy, R. Haushalter (1984)
Synthesis of tin-tellurium polyanions: structure of (Me4N)4Sn2Te6Inorganic Chemistry, 23
Zhengbao Wang, A. Mitra, Huanting Wang, Limin Huang, Yushan Yan (2001)
Pure Silica Zeolite Films as Low‐k Dielectrics by Spin‐On of Nanoparticle SuspensionsAdvanced Materials, 13
M. Wachhold, K. Rangan, Ming Lei, M. Thorpe, S. Billinge, V. Petkov, J. Heising, M. Kanatzidis (2000)
Mesostructured Metal Germanium Sulfide and Selenide Materials Based on the Tetrahedral [Ge4S10]4− and [Ge4Se10]4− Units: Surfactant Templated Three-Dimensional Disordered Frameworks Perforated with Worm HolesIEEE Journal of Solid-state Circuits, 152
B. Krebs (1983)
Thio‐ and Seleno‐Compounds of Main Group Elements—Novel Inorganic Oligomers and PolymersAngewandte Chemie, 22
T. Story, Chw Swüste, Pjt Eggenkamp, Hjm Swagten, de Jonge (1996)
Electron Paramagnetic Resonance Knight Shift in Semimagnetic (Diluted Magnetic) Semiconductors.Physical review letters, 77 13
J. Beck, J. Vartuli, W. Roth, M. Leonowicz, C. Kresge, K. Schmitt, C. Chu, D. Olson, E. Sheppard, S. Mccullen, J. Higgins, J. Schlenker (1992)
A new family of mesoporous molecular sieves prepared with liquid crystal templatesJournal of the American Chemical Society, 114
L. Pidol, D. Grosso, Galo Soler-Illia, E. Crepaldi, C. Sanchez, P. Albouy, H. Amenitsch, P. Euzen (2002)
Hexagonally organised mesoporous aluminium–oxo–hydroxide thin films prepared by the template approach. In situ study of the structural formationJournal of Materials Chemistry, 12
M. MacLachlan, N. Coombs, G. Ozin (1999)
Non-aqueous supramolecular assembly of mesostructured metal germanium sulphides from (Ge4S10)4− clustersNature, 397
A. Pirani, H. Mercier, D. Dixon, H. Borrmann, G. Schrobilgen (2001)
Syntheses, vibrational spectra, and theoretical studies of the adamantanoid Sn(4)Ch(10)(4-) (Ch = Se, Te) anions: X-ray crystal structures of [18-crown-6-K](4)[Sn4Se10]*5en and [18-crown-6-K](4)[Sn4Te10]*3en*2THF.Inorganic chemistry, 40 19
S. Bagshaw, T. Pinnavaia (1996)
Mesoporous Alumina Molecular SievesAngewandte Chemie, 35
Q. Huo, D. Margolese, Ulrike Ciesla, P. Feng, T. Gier, P. Sieger, R. Leon, Pierre Petroff, F. Schüth, G. Stucky (1994)
Generalized synthesis of periodic surfactant/inorganic composite materialsNature, 368
Z. Tian, W. Tong, Jin-yun Wang, Niangao Duan, V. Krishnan, S. Suib (1997)
Manganese oxide mesoporous structures: Mixed-valent semiconducting catalystsScience, 276
K. Rangan, P. Trikalitis, C. Canlas, T. Bakas, D. Weliky, M. Kanatzidis (2002)
Hexagonal Pore Organization in Mesostructured Metal Tin Sulfides Built with [Sn2S6]4-ClusterNano Letters, 2
P. Alberius, Karen Frindell, R. Hayward, E. Kramer, G. Stucky, B. Chmelka (2002)
General Predictive Syntheses of Cubic, Hexagonal, and Lamellar Silica and Titania Mesostructured Thin Films§Chemistry of Materials, 14
A. Weiss (1969)
Organic Derivatives of Clay Minerals, Zeolites, and Related Minerals
A. Sayari (1996)
Catalysis by Crystalline Mesoporous Molecular SievesChemistry of Materials, 8
D. Antonelli, J. Ying (1996)
Synthesis of a Stable Hexagonally Packed Mesoporous Niobium Oxide Molecular Sieve Through a Novel Ligand‐Assisted Templating MechanismAngewandte Chemie, 35
A. Riley, S. Tolbert (2003)
Synthesis of periodic hexagonal surfactant templated platinum tin tellurides: narrow band gap inorganic/organic composites.Journal of the American Chemical Society, 125 15
B. Scott, M. Bartl, G. Wirnsberger, G. Stucky (2003)
Energy transfer in dye-doped mesostructured compositesJournal of Physical Chemistry A, 107
F. Menger, C. Littau (1993)
Gemini surfactants: a new class of self-assembling moleculesJournal of the American Chemical Society, 115
S. Tolbert, C. Landry, G. Stucky, B. Chmelka, P. Norby, J. Hanson, A. Monnier (2001)
Phase Transitions in Mesostructured Silica/Surfactant Composites: Surfactant Packing and the Role of Charge Density MatchingChemistry of Materials, 13
T. Sun, J. Ying (1998)
Synthesis of Microporous Transition Metal Oxide Molecular Sieves with Bifunctional Templating Molecules.Angewandte Chemie, 37 5
C. Landry, S. Tolbert, K. Gallis, A. Monnier, G. Stucky, P. Norby, J. Hanson (2001)
Phase Transformations in Mesostructured Silica/Surfactant Composites. Mechanisms for Change and Applications to Materials SynthesisChemistry of Materials, 13
Thuc‐Quyen Nguyen, Junjun Wu, V. Doan, B. Schwartz, S. Tolbert (2000)
Control of energy transfer in oriented conjugated polymer-mesoporous silica compositesScience, 288 5466
Junjun Wu, A. Gross, S. Tolbert (1999)
Host−Guest Chemistry Using an Oriented Mesoporous Host: Alignment and Isolation of a Semiconducting Polymer in the Nanopores of an Ordered Silica MatrixJournal of Physical Chemistry B, 103
P. Trikalitis, K. Rangan, M. Kanatzidis (2002)
Platinum chalcogenido MCM-41 analogues. High hexagonal order in mesostructured semiconductors based on Pt(2+) and [Ge(4)Q(10)](4-) (Q = S, Se) and [Sn(4)Se(10)](4-) adamantane clusters.Journal of the American Chemical Society, 124 11
K. Rangan, S. Billinge, V. Petkov, J. Heising, M. Kanatzidis (1999)
Aqueous Mediated Synthesis of Mesostructured Manganese Germanium Sulfide with Hexagonal OrderChemistry of Materials, 11
M. Wong, D. Antonelli, J. Ying (1997)
Synthesis and characterization of phosphated mesoporous zirconium oxideNanostructured Materials, 9
C. Kresge, M. Leonowicz, W. Roth, J. Vartuli, J. Beck (1992)
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanismNature, 359
A. Monnier, Ferdi Schüth, Ferdi Schüth, Ferdi Schüth, Q. Huo, D. Kumar, D. Margolese, R. Maxwell, G. Stucky, M. Krishnamurty, Pierre Petroff, A. Firouzi, M. Janicke, B. Chmelka (1993)
Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate MesostructuresScience, 261
Galo Soler-Illia, Andrea Louis, C. Sanchez (2002)
Synthesis and Characterization of Mesostructured Titania-Based Materials through Evaporation-Induced Self-AssemblyChemistry of Materials, 14
In this work, we demonstrate the synthesis of semiconducting tin telluride inorganic/organic composite materials with nanoscale periodicity prepared using solution phase self-assembly. Oligomerization of anionic SnTe 4 4− clusters by halogen-mediated tellurium elimination in the presence of surfactant leads to the formation of a meosotructured composite. The composites initially forms as a mixture of mesophases, usually some combination of a layered phase and a phase based on cylindrical building blocks. Post synthetic treatment leads to a solid-state structural change which converts the composites to a single mesophase architecture with a hexagonal honeycomb (p6mm) morphology on the nanometer length scale. A by product of this reaction, however, is bulk tellurium. Changes in the electronic structure of the materials during synthesis and solid-state restructuring are probed using electron spin resonance (ESR) spectroscopy.
Research on Chemical Intermediates – Springer Journals
Published: Apr 25, 2009
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