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A particular Temperature-Programmed Desorption (TPD) method, called ‘Intermittent TPD’, has been applied to the decomposition of oxygen groups naturally present at the surface of a microporous active carbon. It is shown that this method provides more information on the kinetics of the thermal decomposition of these species than the classical TPD technique. The main result is that the decomposition of these oxygen groups occurs in at least 7 distinct stages which have been characterized by their apparent activation energy and the corresponding frequency factor. The present study underlines the usefulness of ITPD for studying the rate of desorption of gases from powdered samples with a strongly heterogeneous surface.
Journal of Thermal Analysis and Calorimetry – Springer Journals
Published: May 1, 1998
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