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Studies on (NaCl) x (KBr) y-x (KI)1-y solid solutions: 1. Lattice and thermal parameters

Studies on (NaCl) x (KBr) y-x (KI)1-y solid solutions: 1. Lattice and thermal parameters Solid solutions of NaCl, KBr and KI were prepared by the melt method for the first time. Densities and refractive indices of all the prepared solid solutions were determined and also used for the estimation of the bulk composition in the crystal. Lattice parameters and thermal parameters like Debye–Waller factor, mean square amplitude of vibration, Debye temperature and Debye frequency were determined from the X-ray powder diffraction data. The observed lattice parameters showed the existence of three phases in solid solutions each nearly corresponds to NaCl, KBr and KI. The thermal parameters show a highly non-linear bulk composition dependence. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Materials Science Springer Journals

Studies on (NaCl) x (KBr) y-x (KI)1-y solid solutions: 1. Lattice and thermal parameters

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References (15)

Publisher
Springer Journals
Copyright
Copyright © 2006 by Springer Science+Business Media, LLC
Subject
Materials Science; Materials Science, general; Characterization and Evaluation of Materials; Polymer Sciences; Continuum Mechanics and Mechanics of Materials; Crystallography and Scattering Methods; Classical Mechanics
ISSN
0022-2461
eISSN
1573-4803
DOI
10.1007/s10853-006-0999-2
Publisher site
See Article on Publisher Site

Abstract

Solid solutions of NaCl, KBr and KI were prepared by the melt method for the first time. Densities and refractive indices of all the prepared solid solutions were determined and also used for the estimation of the bulk composition in the crystal. Lattice parameters and thermal parameters like Debye–Waller factor, mean square amplitude of vibration, Debye temperature and Debye frequency were determined from the X-ray powder diffraction data. The observed lattice parameters showed the existence of three phases in solid solutions each nearly corresponds to NaCl, KBr and KI. The thermal parameters show a highly non-linear bulk composition dependence.

Journal

Journal of Materials ScienceSpringer Journals

Published: Nov 7, 2006

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