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- Publisher
- Springer Journals
- Copyright
- Copyright © 2005 by Springer-Verlag
- Subject
- Chemistry
- ISSN
- 0303-402X
- eISSN
- 1435-1536
- DOI
- 10.1007/s00396-004-1200-6
- Publisher site
- See Article on Publisher Site
Abstract
The mixed micelles of sodium dodecyl sulphate (SDS) with Brij35 and Brij 97 were studied separately by fluorescence measurement using pyrene as fluorescent probe. In the range of 0–1.0 mole fraction (X) of added SDS to Brij solutions, the cmc value of the mixed micelles varies from 0.085 to 8 mmol with Brij 35 and 0.04 to 8 mmol with Brij 97. The aggregation number also changes. A measure of the stability of mixed micelles is also presented. The interaction parameter β12 and the chain–chain contribution parameter (B 1) are extracted from the analysis of the results. This parameter B 1 is related to the standard free energy change associated with the introduction of one ionic species into a nonionic micelle coupled with the release of one nonionic species from the micelle. The clouding behaviour of Brij 97 in the presence of SDS was investigated and the associated thermodynamic parameters of clouding were generated and discussed.
Journal
Colloid Polymer Science – Springer Journals
Published: Mar 12, 2005