The results of a study of reactivity of Al(III) complexes with acido ligands (Cl−, OH−) and substituted phthalocyanine, containing 4 and 8 substituents (Cl, Br, NO2 or COOH) in different positions of annelated benzene residues, are reviewed. Reactivity of coordinated phthalocyanines is studied by quantum-chemical and spectrophotometric methods for acid-base reactions and reactivity of coordination core is estimated by chemical kinetics methods using reactions of dissociation at the Al-N bonds. The Hammett-Taft correlation equations are derived for mono-and diprotonated tetrasubstituted phthalocyanines of Al(III) with positive ρ values of 10.2 and 59.8, respectively
Russian Journal of Coordination Chemistry – Springer Journals
Published: Mar 20, 2006
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