Synthesis of a series of phosphides (AlP, CrP, NbP, MoP, and WP) by reactions of powdered metals with a melt of lithium metaphosphate LiPO3 was studied. Thermodynamic parameters (ΔH 0 2 9 8, ΔS 0 2 9 8, ΔG 0 2 9 8, and ΔG 0 1 2 7 3) of the reactions were calculated and their temperature modes were optimized on the basis of the standard thermodynamic characteristics of the initial substances and the reaction products. X-ray patterns of the powders of the obtained compounds are presented.
Russian Journal of Applied Chemistry – Springer Journals
Published: Oct 13, 2004
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