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- Publisher
- Springer Journals
- Copyright
- Copyright © 2017 by Pleiades Publishing, Ltd.
- Subject
- Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
- ISSN
- 1070-4272
- eISSN
- 1608-3296
- DOI
- 10.1134/S1070427217020045
- Publisher site
- See Article on Publisher Site
Abstract
Study of the photocatalytic activity of nanomaterials based on potassium polytitanate modified with transition metal ions (Ni2+, Cr3+, Cu2+) demonstrated that the cation composition, morphology of photocatalyst particles, and their size strongly affect the photocatalytic activity. The rate of the photoinduced hydrogen evolution from the aqueous-alcoholic solution grows in the series of potassium polytitanates modified with Cu2+, Ni2+, Cr3+ ions, and that from pure water, for potassium polytitanates modified with Ni2+,Cr3+, Cu2+ ions. The capacity for intercalation of water into the interlayer space does not strongly affect the rate of the photoinduced hydrogen evolution. It was shown that potassium polytitanate modified with Cr3+ ions has the maximum quantum efficiency (30%).
Journal
Russian Journal of Applied Chemistry – Springer Journals
Published: Jun 2, 2017