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- Publisher
- Springer Journals
- Copyright
- Copyright © 2015 by Springer Science+Business Media Dordrecht
- Subject
- Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
- ISSN
- 0922-6168
- eISSN
- 1568-5675
- DOI
- 10.1007/s11164-015-2248-2
- Publisher site
- See Article on Publisher Site
Abstract
An efficient acidic functionalization of mesoporous silica LUS-1 (Laval University silica) was carried out by grafting and oxidation of (3-mercaptopropyl)trimethoxysilane. The functionalized LUS-1 was characterized by different methods such as TGA, XRD, BET and SEM methods and its catalytic activity for one-pot synthesis of xanthene derivatives via the three-component condensation reaction of aromatic aldehydes and dimedone has been reported. The short reaction time, excellent yields, simple work-up procedure, and environmentally friendly conditions are particular advantages of this method. Antibacterial and antifungal activities of synthesized compounds were measured against gram-positive and gram-negative bacteria and fungus. Only compound 9-(2,4-dichlorophenyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione (3h) showed activity against Bacillus subtilis.
Journal
Research on Chemical Intermediates – Springer Journals
Published: Sep 4, 2015