Access the full text.
Sign up today, get DeepDyve free for 14 days.
N. Sinha, N. Munichandraiah (2008)
Electrochemical conversion of LiMn2O4 to MgMn2O4 in aqueous electrolytesElectrochemical and Solid State Letters, 11
Niya Sa, Hao Wang, D. Proffit, Albert Lipson, B. Key, Ming Liu, Zhenxing Feng, T. Fister, Yang Ren, Cheng-Jun Sun, J. Vaughey, P. Fenter, K. Persson, A. Burrell (2016)
Is alpha-V 2 O 5 a cathode material for Mg insertion batteries?Journal of Power Sources, 323
Zhen Li, B. Guan, Jintao Zhang, X. Lou (2017)
A Compact Nanoconfined Sulfur Cathode for High-Performance Lithium-Sulfur BatteriesJoule, 1
F. Critchfield, E. Bishop (1961)
Water Determination by Reaction with 2,2-DimethoxypropaneAnalytical Chemistry, 33
S. Panero, B. Scrosati, H. Sumathipala, W. Wieczorek (2007)
Dual-composite polymer electrolytes with enhanced transport propertiesJournal of Power Sources, 167
Chia‐Chin Chang, Li-Jane Her, Li Chen, Yen-yu Lee, Shyh-Jiun Liu, H. Tien (2007)
2,2-Dimethoxy-propane as electrolyte additive for lithium-ion batteriesJournal of Power Sources, 163
(2016)
2016) MoO 2/Mo 2 C/C spheres as anode materials for lithium ion batteries
J. Hou, Rong Wu, Pengjun Zhao, Aimin Chang, G. Ji, Bo Gao, Qing Zhao (2013)
Graphene-TiO2(B) nanowires composite material: Synthesis, characterization and application in lithium-ion batteriesMaterials Letters, 100
M. Ihsan, Hongqiang Wang, S. Majid, Jianping Yang, S. Kennedy, Zaiping Guo, Huakun Liu (2016)
MoO2/Mo2C/C spheres as anode materials for lithium ion batteriesCarbon, 96
B. A., Z. Zhao‐Karger, T. Diemant, Venkata Sai, Kiran Chakravadhanula, N. Schwarzburger, M. Cambaz, J. Behm, C. Kübel, M. Fichtner (2016)
Performance study of magnesium-sulfur battery using a graphene based sulfur composite cathode electrode and a non-nucleophilic Mg electrolyte.Nanoscale, 8 6
Seonbaek Ha, Yong-Woon Lee, S. Woo, B. Koo, Jeom‐Soo Kim, Jaephil Cho, Kyu-Tae Lee, N. Choi (2014)
Magnesium(II) bis(trifluoromethane sulfonyl) imide-based electrolytes with wide electrochemical windows for rechargeable magnesium batteries.ACS applied materials & interfaces, 6 6
M. Ihsan, Hongqiang Wang, S. Majid, Jianping Yang, S. Kennedy, Zaiping Guo, H. Liu (2017)
MoO 2 / Mo 2 C / C spheres as anode materials for lithium ion batteries
Xuejun Zhou, Jing Tian, Jiulin Hu, Chilin Li (2018)
High Rate Magnesium–Sulfur Battery with Improved Cyclability Based on Metal–Organic Framework Derivative Carbon HostAdvanced Materials, 30
D. McNulty, H. Geaney, Darragh Buckley, C. O’Dwyer (2018)
High capacity binder-free nanocrystalline GeO2 inverse opal anodes for Li-ion batteries with long cycle life and stable cell voltageNano Energy, 43
Ultrathin V 2 O 5 nanosheet cathodes : realizing ultrafast reversible lithium storage
Aobing Du, Zhonghua Zhang, Hongtao Qu, Z. Cui, Lixin Qiao, Longlong Wang, J. Chai, Tao Lu, Shanmu Dong, Tiantian Dong, Huimin Xu, Xin-hong Zhou, G. Cui (2017)
An efficient organic magnesium borate-based electrolyte with non-nucleophilic characteristics for magnesium–sulfur batteryEnergy and Environmental Science, 10
M. Mao, Feilong Yan, Chunyu Cui, Jianmin Ma, Ming Zhang, Taihong Wang, Chunsheng Wang (2017)
Pipe-Wire TiO2-Sn@Carbon Nanofibers Paper Anodes for Lithium and Sodium Ion Batteries.Nano letters, 17 6
S. Kang, Sung-Chul Lim, H. Kim, J. Heo, Sunwook Hwang, Minchul Jang, Dookyong Yang, Seung‐Tae Hong, Hochun Lee (2017)
Non-Grignard and Lewis Acid-Free Sulfone Electrolytes for Rechargeable Magnesium BatteriesChemistry of Materials, 29
O. Tutusaus, R. Mohtadi, T. Arthur, Fuminori Mizuno, Emily Nelson, Y. Sevryugina (2015)
An Efficient Halogen-Free Electrolyte for Use in Rechargeable Magnesium Batteries.Angewandte Chemie, 54 27
Long Chen, Yutao Li, Shuai Li, Li‐Zhen Fan, C. Nan, J. Goodenough (2017)
PEO/garnet composite electrolytes for solid-state lithium batteries: From “ceramic-in-polymer” to “polymer-in-ceramic”Nano Energy, 46
Hongyu Zhang, K. Ye, Shuangxi Shao, Xin Wang, Kui Cheng, X. Xiao, Guiling Wang, D. Cao (2017)
Octahedral magnesium manganese oxide molecular sieves as the cathode material of aqueous rechargeable magnesium-ion batteryElectrochimica Acta, 229
Hind and, V. Grassian (2003)
Phase Transitions in Magnesium Nitrate Thin Films: A Transmission FT-IR Study of the Deliquescence and Efflorescence of Nitric Acid Reacted Magnesium Oxide InterfacesJournal of Physical Chemistry B, 107
Minghao Zhang, Alex MacRae, Y. Meng (2016)
Investigation of Anatase-TiO2 As an Efficient Electrode Material for Magnesium-Ion Batteries
A. Schenau, W. Groeneveld, J. Reedijk (2010)
Alcohols as ligands. Part II: Metal(II) salts containing coordinated methanolRecueil des Travaux Chimiques des Pays-Bas, 91
(2015)
Sevryugina YV (2015) An efficient halogen-free electrolyte for use in rechargeable magnesium batteries
Mazdida N.S. (2013)
Structural, thermal and conductivity studies of magnesium nitratealumina composite solid electrolytes prepared via sol-gel method
X. Rui, Ziyang Lu, Hong Yu, Dan Yang, H. Hng, T. Lim, Q. Yan (2013)
Ultrathin V2O5 nanosheet cathodes: realizing ultrafast reversible lithium storage.Nanoscale, 5 2
Xiu Li, Zhibo Yang, Yujun Fu, L. Qiao, Dan Li, H. Yue, D. He (2015)
Germanium anode with excellent lithium storage performance in a germanium/lithium-cobalt oxide lithium-ion battery.ACS nano, 9 2
M Zhang, AC MacRae, H Liu, YS Meng (2016)
Communication—investigation of anatase-TiO2 as an efficient electrode material for magnesium-ion batteriesJ Electrochem Soc, 163
Zhonghua Zhang, Z. Cui, Lixin Qiao, Jing Guan, Huimin Xu, Xiaogang Wang, P. Hu, Huiping Du, Shizhen Li, Xin-hong Zhou, Shanmu Dong, Zhihong Liu, G. Cui, Liquan Chen (2017)
Novel Design Concepts of Efficient Mg‐Ion Electrolytes toward High‐Performance Magnesium–Selenium and Magnesium–Sulfur BatteriesAdvanced Energy Materials, 7
M. Natal-Santiago, J. Dumesic (1998)
Microcalorimetric, FTIR, and DFT Studies of the Adsorption of Methanol, Ethanol, and 2,2,2-Trifluoroethanol on SilicaJournal of Catalysis, 175
D. Su, Guoxiu Wang (2013)
Single-crystalline bilayered V2O5 nanobelts for high-capacity sodium-ion batteries.ACS nano, 7 12
Zheng-yong Yuan, Q. Jiang, C. Feng, Xiao Chen, Zaiping Guo (2017)
Synthesis and Performance of Tungsten Disulfide/Carbon (WS2/C) Composite as Anode MaterialJournal of Electronic Materials, 47
Z. Zhao‐Karger, Maria Bardaji, O. Fuhr, M. Fichtner (2017)
A new class of non-corrosive, highly efficient electrolytes for rechargeable magnesium batteriesJournal of Materials Chemistry, 5
M. Rashad, Hongzhang Zhang, M. Asif, K. Feng, Xianfeng Li, Huamin Zhang (2018)
Low-Cost Room-Temperature Synthesis of NaV3O8·1.69H2O Nanobelts for Mg Batteries.ACS applied materials & interfaces, 10 5
D. Samuel, Carl Steinhauser, Jeffrey Smith, A. Kaufman, M. Radin, Junichi Naruse, Hidehiko Hiramatsu, Donald Siegel (2017)
Ion Pairing and Diffusion in Magnesium Electrolytes Based on Magnesium Borohydride.ACS applied materials & interfaces, 9 50
H. Yoo, Yanliang Liang, Hui Dong, Junhao Lin, Hua Wang, Yi-sheng Liu, Lu Ma, Tianpin Wu, Yifei Li, Qiang Ru, Y. Jing, Qinyou An, Wu Zhou, Jinghua Guo, Jun Lu, S. Pantelides, Xiaofeng Qian, Yan Yao (2017)
Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteriesNature Communications, 8
Z. Zhao‐Karger, Xiangyu Zhao, Di Wang, T. Diemant, R. Behm, M. Fichtner (2015)
Performance Improvement of Magnesium Sulfur Batteries with Modified Non‐Nucleophilic ElectrolytesAdvanced Energy Materials, 5
D. Aurbach, Z. Lu, A. Schechter, Y. Gofer, Haim Gizbar, R. Turgeman, Y. Cohen, M. Moshkovich, E. Levi (2000)
Prototype systems for rechargeable magnesium batteriesNature, 407
C. Tan, N. Farhana, N. Saidi, S. Ramesh, K. Ramesh (2018)
Conductivity, dielectric studies and structural properties of P(VA-co-PE) and its application in dye sensitized solar cellOrganic Electronics, 56
R. Mohtadi, M. Matsui, T. Arthur, Son-Jong Hwang (2012)
Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery**Angewandte Chemie (International Ed. in English), 51
Hongyu Zhang, K. Ye, K. Zhu, Ruibai Cang, Jun Yan, Kui Cheng, Guiling Wang, D. Cao (2017)
The FeVO4·0.9H2O/Graphene composite as anode in aqueous magnesium ion batteryElectrochimica Acta, 256
I. Shterenberg, Michael Salama, Y. Gofer, E. Levi, D. Aurbach (2014)
The challenge of developing rechargeable magnesium batteriesMRS Bulletin, 39
Linqi Zeng, Nan-qing Wang, Jun Yang, Jiulin Wang, Yanna Nuli (2017)
Application of a Sulfur Cathode in Nucleophilic Electrolytes for Magnesium/Sulfur BatteriesJournal of The Electrochemical Society, 164
Long Chen, Li‐Zhen Fan (2018)
Dendrite-free Li metal deposition in all-solid-state lithium sulfur batteries with polymer-in-salt polysiloxane electrolyteEnergy Storage Materials
Functional compatible electrolyte with Mg2+ intercalation cathodes represents one of the largest obstacles in the development of practical Mg batteries MBs. In current work, we report for the first time magnesium hexakis(methanol)-dinitrate complex (MHMD) electrolyte product reaction of 2,2-dimethoxypropane with magnesium nitrate hexahydrate via ‘Solvent-in-Salt’ method. 2,2-Dimethoxypropane as a water scavenger can capture reducible molecules like H2O and dehydrate Mg(NO3)2.6H2O to form magnesium hexakis(methanol)-dinitrate complex. Meanwhile, Mg cloud bonds will become weak—something which frees up the mobility of Mg2+. This electrolyte exhibits high ionic conductivity with low activation energy ~ 0.18 eV. The general aim of the investigation was to demonstrate a potential application of MHMD electrolyte in Mg-ion cell. Mg cells were analyzed with the use of cyclic voltammetry (CV), galvanostatic charging/discharging tests, and electrochemical impedance spectroscopy. A comparative study between different cathodes like V2O5, GeO2, TiO2, and S using MHMD electrolyte was performed. The S cathode has an initial discharge capacity of 370 mAh g−1 and retained a reversible capacity at 60 mAh g−1 after 20 cycles exhibiting better electrochemical performances than those of V2O5, GeO2, and TiO2 cathodes. This work opens up a new pathway to explore new electrolytic materials for MBs with high performance.
Journal of Solid State Electrochemistry – Springer Journals
Published: May 8, 2018
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.