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Equations for low-temperature adsorption isotherms, isosteric heats of adsorption, and heat capacities of the adsorbed phase are developed for monolayer localized adsorption of monoatomic gases on heterogeneous solid surfaces. The model assumes that adsorption sites having various adsorption energies are distributed on the adsorbent surface completely at random. The interactions between adsorbed molecules are treated in the quasichemical approximation. The equations are illustrated by numerous model calculations.
Journal of Low Temperature Physics – Springer Journals
Published: Nov 3, 2004
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