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- Publisher
- Springer Journals
- Copyright
- Copyright © 2005 by Springer Science+Business Media, Inc.
- Subject
- Chemistry; Inorganic Chemistry; Organic Chemistry; Chemistry/Food Science, general
- ISSN
- 1066-5285
- eISSN
- 1573-9171
- DOI
- 10.1007/s11172-005-0367-4
- Publisher site
- See Article on Publisher Site
Abstract
The vibrational spectra of tetravalent metal halides (M = Si, Ge, Sn) and the corresponding dihalocarbene analogs MIIHal2, obtained by the authors, and the relevant published data are compared. The spectra of the MIIHal2 species exhibit inversion of the M-Hal stretching frequencies (νs(MIIHal) > ν as(MIIHal)). This can be used for analytical purposes and allows one to distinguish between the spectra of the MIV and MII halides. The IR and Raman spectra of the complexes of dihalogermylenes and -stannylenes with triphenylphosphine and 1,4-dioxane also exhibit inversion of the ν(MHal) stretching frequencies. This confirms the conclusion drawn earlier based on the analysis of the geometric parameters and reactivities of the complexes in question that the divalent state of the M atom in these species is retained.
Journal
Russian Chemical Bulletin – Springer Journals
Published: Nov 30, 2005