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J. Hinatsu, F. Foulkes (1989)
Diffusion Coefficients for Copper (II) in Aqueous Cupric Sulfate‐Sulfuric Acid SolutionsJournal of The Electrochemical Society, 136
J. Daschbach, S. Pons, M. Fleischmann (1989)
The behavior of microdisk and microring electrodes: Application of Neumann's integral theorem to the prediction of the steady state response of microdisks. Numerical illustrationsJournal of Electroanalytical Chemistry, 263
A. Arvia, J. Bazán, J. Carrozza (1966)
Electrochemical study of the diffusion of cupric ion in aqueous and aqueous-glycerol solutions containing sulphuric acidElectrochimica Acta, 11
Lutz Gerth, F. Lapicque (1996)
Importance of Surface Preparation in Electrochemical Investigations of the Copper System in Dilute Copper Sulfate SolutionsJournal of The Electrochemical Society, 143
A. McDonald, F. Fan, A. Bard (1986)
Electrochemistry in near-critical and supercritical fluids. 2. Water. Experimental techniques and the copper(II) systemThe Journal of Physical Chemistry, 90
G. Gunawardena, G. Hills, I. Montenegro, B. Scharifker (1982)
Electrochemical nucleation: Part I. General considerationsJournal of Electroanalytical Chemistry, 138
B. Conway (1974)
Modern Aspects of Electrochemistry
T. O’keefe, L. Hurst (1978)
The effect of antimony, chloride ion, and glue on copper electrorefiningJournal of Applied Electrochemistry, 8
R. Wightman (1988)
Voltammetry with Microscopic Electrodes in New DomainsScience, 240
A. Biswas, W. Davenport (1976)
Extractive metallurgy of copper
T. Subbaiah, Sudipta Das (1989)
Physico-chemical properties of copper electrolytesMetallurgical and Materials Transactions B, 20
T. Quickenden, X. Jiang (1984)
The diffusion coefficient of copper sulphate in aqueous solutionElectrochimica Acta, 29
C. Wilke, M. Eisenberg, C. Tobias (1953)
Correlation of Limiting Currents under Free Convection ConditionsJournal of The Electrochemical Society, 100
J. Macpherson, P. Unwin (1994)
A Novel Approach to the Study of Dissolution Kinetics Using the Scanning Electrochemical Microscope: Theory and Application to Copper Sulfate Pentahydrate Dissolution in Aqueous Sulfuric Acid SolutionsThe Journal of Physical Chemistry, 98
J. Bazán, A. Arvia (1965)
The diffusion of ferro- and ferricyanide ions in aqueous solutions of sodium hydroxide☆Electrochimica Acta, 10
T. Quickenden, Qingzhong Xu (1996)
Toward a Reliable Value for the Diffusion Coefficient of Cupric Ion in Aqueous SolutionJournal of The Electrochemical Society, 143
A. Correia, S. Machado, J. Sampaio, L. Avaca (1996)
Electrochemical nucleation on disc-shaped ultramicroelectrodes: theoretical aspectsJournal of Electroanalytical Chemistry, 407
B. Scharifker, G. Hills (1983)
Theoretical and experimental studies of multiple nucleationElectrochimica Acta, 28
S. Goldbach, B. Bossche, T. Daenen, J. Deconinck, F. Lapicque (2000)
Copper deposition on micropatterned electrodes from an industrial acid copper plating bathJournal of Applied Electrochemistry, 30
M. Moats, J. Hiskey, D. Collins (2000)
The effect of copper, acid, and temperature on the diffusion coefficient of cupric ions in simulated electrorefining electrolytesHydrometallurgy, 56
M. Sun, T. O’keefe (1992)
The effect of additives on the nucleation and growth of copper onto stainless steel cathodesMetallurgical Transactions B, 23
Few data are available for diffusion coefficients measured in industrial copper electrolytes. In the present work the influence of copper concentration (19.9–58.1 g dm−3), temperature (20–60°C) and concentrations levelling agents i.e. animal glue (0–5 mg dm−3) and thiourea (0–5 mg dm−3) on diffusion coefficients of copper was studied in industrial copper refinery electrolytes. Chronoamperometry at ultramicroelectrodes was used as an electrochemical technique. Apparent bulk diffusion coefficients were calculated on the basis of the theory of electrochemical nucleation on disc-shaped ultramicroelectrodes. Increasing copper concentration decreased the apparent bulk diffusion coefficient of copper and diffusion coefficients followed the Arrhenius temperature relationship. The experimental activation energy was 26.8 kJ mol−1. The influence of levelling agents on diffusion coefficients was not strong in the studied concentration range of animal glue and thiourea.
Journal of Applied Electrochemistry – Springer Journals
Published: Jul 27, 2007
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