Keywords Ionic liquid Active intermediate Oxidation Green chemistry DFT Introduction Reducing the waste of chemical reactions may be the most concerning issue for developing sustainable processes, both in laboratory and at industrial scales. For this purpose, controlling the emission of hazardous waste is easier than puriﬁcation of the products or waste treatment. Oxidation of organic compounds is a routine method for the synthesis of a plethora of valuable building blocks and derivatives in chemistry . In this regard, hydrogen peroxide (H O ) is a promising selection since it is a cheap and 2 2 commercially available oxidant, and more importantly, water is the sole by-product of the oxidation reaction. Compared to molecular oxygen or air, the oxidation reaction using H O is more controllable . However, H O is known as a ‘‘lazy’’ 2 2 2 2 oxidant in organic synthesis. In most cases, a desired yield could be obtained only by applying some heavy metal oxides or complexes such as tungsten (W) [3, 4], molybdenum (Mo)  or manganese (Mn) [6, 7]. However, the applied metal catalysts are usually expensive and, in most cases, the separation and puriﬁcation process of the products and
Research on Chemical Intermediates – Springer Journals
Published: Oct 24, 2016
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera