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J Mater Sci (2006) 41:6185–6188 DOI 10.1007/s10853-006-0161-1 LETTE R Effect of CaF on the sintering and thermal expansion of La Sr Cr O 0.85 0.15 0.95 3 Xifeng Ding Æ Lucun Guo Received: 23 September 2004 / Accepted: 29 September 2005 / Published online: 1 August 2006 Springer Science+Business Media, LLC 2006 Lanthanum chromite based perovskite have been widely chromium deficient lanthanum calcium chromites (La 0.7- accepted as ceramic interconnects and as protecting layers Ca Cr O , y = 0.02) could be sintered to 94% theoretical 0.3 1)y 3 for metallic interconnects in solid oxide fuel cells (SOFCs) density at 1,200 C in air. Small particle sizes of the starting because of thier high electronic conductivity, chemical powders prepared by chemical process are usually beneficial stability in both oxidizing and reducing atmospheres as to lower the sintering temperature [7]. Doping with sintering well as their chemical and thermo-mechanical compati- additives is another effective method to densify LaCrO .A bility with other cell components under operating condi- small amount of Sr (VO ) [8] was found to produce high 3 4 2 tions [1, 2]. Strontium-doped LaCrO has emerged as a density LaCrO -based perovskite materials sintered at 3
Journal of Materials Science – Springer Journals
Published: Aug 1, 2006
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