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Mark Griffiths, C. Léon, F. Walsh (2005)
Mass transport in the rectangular channel of a filter-press electrolyzer (the FM01-LC reactor)Aiche Journal, 51
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D. Pletcher, Hantao Zhou, G. Kear, C. Low, F. Walsh, R. Wills (2008)
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D. Pletcher, R. Wills (2005)
A novel flow battery—A lead acid battery based on an electrolyte with soluble lead(II). III. The influence of conditions on battery performanceJournal of Power Sources, 149
A. Hazza, D. Pletcher, R. Wills (2004)
A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II). Part II. Flow cell studiesPhysical Chemistry Chemical Physics, 6
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The history of soluble lead flow batteries is concisely reviewed and recent developments are highlighted. The development of a practical, undivided cell is considered. An in-house, monopolar unit cell (geometrical electrode area 100 cm2) and an FM01-LC bipolar (2 × 64 cm2) flow cell are used. Porous, three-dimensional, reticulated vitreous carbon (RVC) and planar, carbon-HDPE composite electrodes have been used in laboratory flow cells. The performance of such cells under constant current density (10–160 mA cm−2) cycling is examined using a controlled flow rate (mean linear flow velocity <14 cm s-1) at a temperature of approximately 298 K. Voltage versus time and voltage versus current density relationships are considered. High charge (<90%), voltage (<80%) and energy (<70%) efficiencies are possible. Possible failure modes encountered during early scale-up from a small, laboratory flow cell to larger, pilot-scale cells are discussed.
Journal of Applied Electrochemistry – Springer Journals
Published: Mar 1, 2009
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