Cu(In,Ga)Se2 absorbers prepared by electrodeposition for low-cost thin-film solar cells

Cu(In,Ga)Se2 absorbers prepared by electrodeposition for low-cost thin-film solar cells Reducing the manufacturing cost of solar cells is necessary to their industrial production. Electrodepositing is an effective, non-vacuum method which is very suitable for cutting the manufacturing cost of thin films as well as developing its large-scale industrial production. In this study, about 1-μm-thick Cu(In,Ga)Se2 (CIGS) precursors were electrodeposited on Mo/glass substrates in aqueous solution utilizing a three-electrode potentiostatic system. Triethanolamine was used as complexing agent, and all parameters of electrodeposition were precisely controlled. After that, the electrodeposited precursors were selenized in a Se atmosphere with different heating ramp rates (60 and 600 °C·min−1). High-quality CIGS films were obtained, and their characteristics were investigated by X-ray fluorescence, scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, Raman spectra and near-infrared–visible (NIR-Vis) spectra. The results reveal that there are many differences between the properties of the films under different heating rates. Finally, CIGS solar cells were fabricated using a fast and a slow heating rate. The maximum efficiencies achieved for the films selenized at 60 and 600 °C·min−1 are 3.15% and 0.71%, respectively. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Rare Metals Springer Journals

Cu(In,Ga)Se2 absorbers prepared by electrodeposition for low-cost thin-film solar cells

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Publisher
Nonferrous Metals Society of China
Copyright
Copyright © 2017 by The Nonferrous Metals Society of China and Springer-Verlag GmbH Germany
Subject
Materials Science; Metallic Materials; Nanotechnology; Ceramics, Glass, Composites, Natural Materials; Surfaces and Interfaces, Thin Films; Inorganic Chemistry; Physical Chemistry
ISSN
1001-0521
eISSN
1867-7185
D.O.I.
10.1007/s12598-017-0941-6
Publisher site
See Article on Publisher Site

Abstract

Reducing the manufacturing cost of solar cells is necessary to their industrial production. Electrodepositing is an effective, non-vacuum method which is very suitable for cutting the manufacturing cost of thin films as well as developing its large-scale industrial production. In this study, about 1-μm-thick Cu(In,Ga)Se2 (CIGS) precursors were electrodeposited on Mo/glass substrates in aqueous solution utilizing a three-electrode potentiostatic system. Triethanolamine was used as complexing agent, and all parameters of electrodeposition were precisely controlled. After that, the electrodeposited precursors were selenized in a Se atmosphere with different heating ramp rates (60 and 600 °C·min−1). High-quality CIGS films were obtained, and their characteristics were investigated by X-ray fluorescence, scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction, Raman spectra and near-infrared–visible (NIR-Vis) spectra. The results reveal that there are many differences between the properties of the films under different heating rates. Finally, CIGS solar cells were fabricated using a fast and a slow heating rate. The maximum efficiencies achieved for the films selenized at 60 and 600 °C·min−1 are 3.15% and 0.71%, respectively.

Journal

Rare MetalsSpringer Journals

Published: Aug 3, 2017

References

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