The Voronoi-Dirichlet polyhedra (VDP) and the method of intersecting spheres were used to analyze crystal structures of 728 compounds containing 976 crystallographically non-equivalent sorts of LnOn polyhedra (Ln = Er, Tm, Yb, Lu). The Ln C.N. vary from 3 to 10, and 14 sorts of coordination polyhedra are present in the structures. Despite the great diversity of C.N., the volume of the VDP was found to depend only on the nature of the Ln atom and its valence state.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Feb 13, 2006
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