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E. Yoshida, S. Kunugi (2002)
Micelle Formation of Nonamphiphilic Diblock Copolymers through Noncovalent Bond Cross-LinkingMacromolecules, 35
K. Tsuchiya, H. Sakai, T. Saji, M. Abe (2003)
Electrochemical Reaction in an Aqueous Solution of a Ferrocene-Modified Cationic Surfactant Mixed with an Anionic SurfactantLangmuir, 19
J. Eastoe, and Dominguez, Paul Wyatt, A. Beeby, R. Heenan (2002)
Properties of a Stilbene-Containing Gemini Photosurfactant: Light-Triggered Changes in Surface Tension and AggregationLangmuir, 18
E. Yoshida, M. Ohta, Y. Terada (2005)
Reversible control of micellization induced by hydrogen bond crosslinking for a nonamphiphilic diblock copolymer with an α,ω‐diaminePolymers for Advanced Technologies, 16
E. Buhler, A. Dobrynin, J. Desimone, M. Rubinstein (1998)
Light-Scattering Study of Diblock Copolymers in Supercritical Carbon Dioxide: CO2 Density-Induced Micellization TransitionMacromolecules, 31
Yuxin Hu, Michael Krämer, C. Boudreaux, C. McCormick (1995)
Water-Soluble Copolymers. 62. Nonradiative Energy Transfer Studies of pH- and Salt-Responsive Associations in Hydrophobically Modified, Hydrolyzed Maleic Anhydride-Ethyl Vinyl Ether CopolymersMacromolecules, 28
M. Arotçaréna, Bettina Heise, S. Ishaya, A. Laschewsky (2002)
Switching the inside and the outside of aggregates of water-soluble block copolymers with double thermoresponsivity.Journal of the American Chemical Society, 124 14
A. Veronese, Nathalie Berclaz, P. Luisi (1998)
PHOTOINDUCED FORMATION OF BILAYER VESICLESJournal of Physical Chemistry B, 102
Liu You-cheng, Liu Zhong-li, Wu Lung‐min, Chen Ping (1985)
A facile generation of radical cations via the action of nitroxidesTetrahedron Letters, 26
J. Bobbitt, C. Flores (1988)
Organic nitrosonium salts as oxidants in organic chemistryHeterocycles, 27
D. Brouwer, J. Doorn (2010)
Reactions of hydroxycarbonium ions in strong acids VI: Interconversion of trimethyltetrahydrofuryl ions via dicarbonium ions. Relative acidities of superacidsRecueil des Travaux Chimiques des Pays-Bas, 91
Haiqing Yin, Zukang Zhou, Jianbin Huang, Rong Zheng, Yongyi Zhang (2003)
Temperature-induced micelle to vesicle transition in the sodium dodecylsulfate/dodecyltriethylammonium bromide system.Angewandte Chemie, 42 19
I. Dunkin, A. Gittinger, D. Sherrington, P. Whittaker (1994)
A photodestructible surfactantJournal of The Chemical Society, Chemical Communications
Nihal and, N. Abbott (2001)
Comparison of the Surface Activity and Bulk Aggregation of Ferrocenyl Surfactants with Cationic and Anionic HeadgroupsLangmuir, 17
K. Szczubiałka, M. Nowakowska (2003)
Response of micelles formed by smart terpolymers to stimuli studied by dynamic light scatteringPolymer, 44
Shuiqin Zhou, B. Chu (1998)
Laser light scattering study of pressure-induced micellization of a diblock copolymer of poly(1,1-dihydroperfluorooctylacrylate) and poly(vinyl acetate) in supercritical carbon dioxideMacromolecules, 31
E. Yoshida, H. Ogawa (2007)
Micelle formation induced by disproportionation of stable nitroxyl radicals supported on a diblock copolymer.Journal of oleo science, 56 6
J. Mcclain, D. Betts, Dorian Canelas, E. Samulski, J. Desimone, J. Londono, H. Cochran, G. Wignall, D. Chillura-Martino, R. Triolo (1996)
Design of Nonionic Surfactants for Supercritical Carbon DioxideScience, 274
N. Epiotis (1983)
The “Forbidden” World of ChemistryNew Journal of Chemistry, 11
D. Neradovic, and Nostrum, W. Hennink (2001)
Thermoresponsive Polymeric Micelles with Controlled Instability Based on Hydrolytically Sensitive N-Isopropylacrylamide CopolymersMacromolecules, 34
E. Yoshida, S. Kuwayama (2008)
Photolysis-induced micellization of a poly(4-tert-butoxystyrene)-block-polystyrene diblock copolymerColloid and Polymer Science, 286
Pinaki and, A. Blume (2001)
Thermodynamic Characterization of Temperature-Induced Micellization and Demicellization of Detergents Studied by Differential Scanning CalorimetryLangmuir, 17
F. Celso, A. Triolo, F. Triolo, D. Donato, M. Steinhart, M. Kriechbaum, H. Amenitsch, R. Triolo (2002)
SAXS investigation on aggregation phenomena in supercritical CO2The European Physical Journal E, 8
E. Yoshida, S. Kuwayama (2007)
Micelle formation induced by photolysis of a poly(tert-butoxystyrene)-block-polystyrene diblock copolymerColloid and Polymer Science, 285
E. Yoshida, Toru Tanaka (2006)
Oxidation-induced micellization of a diblock copolymer containing stable nitroxyl radicalsColloid and Polymer Science, 285
E. Yoshida, Motonari Tanaka, T. Takata (2005)
Self-assembly control of a pyridine-containing diblock copolymer by perfluorinated counter anions during salt-induced micellizationColloid and Polymer Science, 283
E. Yoshida, S. Kuwayama (2009)
Micelle formation induced by photo-Claisen rearrangement of poly(4-allyloxystyrene)-block-polystyreneColloid and Polymer Science, 287
Albert Lee, V. Bütün, M. Vamvakaki, S. Armes, J. Pople, A. Gast (2002)
Structure of pH-Dependent Block Copolymer Micelles: Charge and Ionic Strength DependenceMacromolecules, 35
W. Brown (1996)
Light Scattering: Principles and development
Wenjun Chen, Gan‐zuo Li, Guo-wei Zhou, Limin Zhai, Zhengmin Li (2003)
pH-induced spontaneous vesicle formation from NaDEHPChemical Physics Letters, 374
M. Bergsma, M. Fielden, J. Engberts (2001)
pH-Dependent Aggregation Behavior of a Sugar-Amine Gemini Surfactant in Water: Vesicles, Micelles, and Monolayers of Hexane-1,6-bis(hexadecyl-1′-deoxyglucitylamine)Journal of Colloid and Interface Science, 243
Steve Leclair, Lizamma Mathew, Martin Giguère, S. Motallebi, Yue Zhao (2003)
Photoinduced Alignment of Ferroelectric Liquid Crystals Using Azobenzene Polymer Networks of Chiral Polyacrylates and PolymethacrylatesMacromolecules, 36
E. Yoshida, Kazuaki Nakamura, T. Takata, T. Endo (1993)
Oxoaminium salts as initiators for cationic polymerization of vinyl monomersJournal of Polymer Science Part A, 31
The block copolymer micellization induced by the disproportionation of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was performed using acids with different acid strengths. A poly(4-vinylbenzyloxy-TEMPO)-block-polystyrene diblock copolymer (PVTEMPO-b-PSt) produced micelles in 1,4-dioxane by the disproportionation of the TEMPO by HNO3, HCl, HClO4, and HSbF6. The acid strength affected the efficiency of the micellization. The acid/VTEMPO molar ratio required for the micellization decreased with an increase in the acid strength: $$ {\text{HNO}}_{\text{3}} < {\text{HCl}} < {\text{HClO}}_{\text{4}} < {\text{HSbF}}_{\text{6}} $$ . The acid strength also made a difference in the hydrodyamic diameter of the micelles. The stronger acid provided larger micelles. This difference in the micellization was based on the difference in the solubility of the oxoaminium salt formed by the disproportionation of the TEMPO and on the steric hindrance of its counter anion.
Colloid Polymer Science – Springer Journals
Published: Sep 23, 2009
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