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Complex Energetic Perchlorates of Cobalt(III) Amminates, with Cyclopentamethylenetetrazole as Ligand

Complex Energetic Perchlorates of Cobalt(III) Amminates, with Cyclopentamethylenetetrazole as Ligand Energetic metal complexes, pentammine(cyclopentamethylenetetrazole)cobalt(III) perchlorate and tetraammine-bis(cyclopentamethylenetetrazole)cobalt(III) perchlorate, were obtained by reaction of aquapentaamminecobalt(III) and diaquatetraamminecobalt(III) ions with cyclopentamethylenetetrazole. Microwave heating was used, together with the conventional convective heating, for thermal activation of the process. The thermal decomposition of the compounds synthesized was studied. The explosive characteristics and toxicity of the metal complexes were determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Complex Energetic Perchlorates of Cobalt(III) Amminates, with Cyclopentamethylenetetrazole as Ligand

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References (5)

Publisher
Springer Journals
Copyright
Copyright © 2005 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
DOI
10.1007/s11167-005-0256-5
Publisher site
See Article on Publisher Site

Abstract

Energetic metal complexes, pentammine(cyclopentamethylenetetrazole)cobalt(III) perchlorate and tetraammine-bis(cyclopentamethylenetetrazole)cobalt(III) perchlorate, were obtained by reaction of aquapentaamminecobalt(III) and diaquatetraamminecobalt(III) ions with cyclopentamethylenetetrazole. Microwave heating was used, together with the conventional convective heating, for thermal activation of the process. The thermal decomposition of the compounds synthesized was studied. The explosive characteristics and toxicity of the metal complexes were determined.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 9, 2005

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