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Chromatographic retention and structure roofing tile effect of isomeres and its fine structure

Chromatographic retention and structure roofing tile effect of isomeres and its fine structure Logarithmic plots of gaschromatographic retention data for different classes of compounds on different pairs of stationary phases have been constructed. A remarkable effect was found. Isomers are spread along parallel lines in a repeated pattern, forming roofing tile series. The scattering of points around isomer lines is real and is a consequence of detailed structure of molecules. Alkanes have been divided into groups that have equal numbers of primary, secondary, tertiary and quaternary carbon atoms. Alkanes of these groups are lying upon straight lines. Lines of all groups are parallel. Code numbers are in numerical order if attached to the position of the lines. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chromatographia Springer Journals

Chromatographic retention and structure roofing tile effect of isomeres and its fine structure

Walraven, J.; Ladon, A.; Keulemans, A.
Chromatographia , Volume 1 (5) – May 1, 1968
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References (6)

Publisher
Springer Journals
Copyright
Copyright © 1968 by Friedr. Vieweg & Sohn GmbH
Subject
Chemistry; Analytical Chemistry; Organic Chemistry; Biochemistry, general; Plant Sciences; Pharmacy; Measurement Science, Instrumentation
ISSN
0009-5893
eISSN
1612-1112
DOI
10.1007/BF02255479
Publisher site
See Article on Publisher Site

Abstract

Logarithmic plots of gaschromatographic retention data for different classes of compounds on different pairs of stationary phases have been constructed. A remarkable effect was found. Isomers are spread along parallel lines in a repeated pattern, forming roofing tile series. The scattering of points around isomer lines is real and is a consequence of detailed structure of molecules. Alkanes have been divided into groups that have equal numbers of primary, secondary, tertiary and quaternary carbon atoms. Alkanes of these groups are lying upon straight lines. Lines of all groups are parallel. Code numbers are in numerical order if attached to the position of the lines.

Journal

Chromatographia – Springer Journals

Published: May 1, 1968

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