Access the full text.
Sign up today, get DeepDyve free for 14 days.
J. Sitter, A. Govaert, E. Grave, D. Chambaere (1978)
MOESSBAUER SPECTROSCOPY AS A TOOL FOR THE INVESTIGATION OF INDUSTRIAL IRON ORE SINTERSChemInform, 9
Lichun Zhang, A. Vasiliev, I. Misirlioglu, R. Ramesh, S. Alpay, M. Aindow (2008)
Cation ordering in epitaxial lead zirconate titanate filmsApplied Physics Letters, 93
C. Rossouw, P. Turner, T. White, A. O'Connor (1989)
Statistical analysis of electron channelling microanalytical data for the determination of site occupancies of impuritiesPhilosophical Magazine Letters, 60
Yngve Larring, T. Norby (2000)
Spinel and Perovskite Functional Layers Between Plansee Metallic Interconnect (Cr‐5 wt % Fe‐1 wt % Y 2 O 3) and Ceramic ( La0.85Sr0.15 ) 0.91MnO3 Cathode Materials for Solid Oxide Fuel CellsJournal of The Electrochemical Society, 147
F. Boer, J. Santen, E. Verwey (1950)
The Electrostatic Contribution to the Lattice Energy of Some Ordered SpinelsJournal of Chemical Physics, 18
K. Mocała, A. Navrotsky (1989)
Structural and Thermodynamic Variation in Nickel Aluminate SpinelJournal of the American Ceramic Society, 72
Jingkang Zhu, Qiuming Gao (2009)
Mesoporous MCo2O4 (M = Cu, Mn and Ni) spinels: Structural replication, characterization and catalytic application in CO oxidationMicroporous and Mesoporous Materials, 124
J. Smyth, T. Mccormick (1988)
Earth science applications of ALCHEMIUltramicroscopy, 26
Yanhong Hu, Lichun Zhang, David Shuman, B. Huey, M. Aindow (2009)
Atomic site occupancies and mechanical response of the eutectic C14 and A15 phases in a quinternary Nb-Mo-Cr-Al-Si alloyScripta Materialia, 60
J. Burdett, G. Price, S. Price (1982)
Role of the crystal-field theory in determining the structures of spinelsJournal of the American Chemical Society, 104
L. Chick, G. Maupin, L. Pederson (1994)
Glycine-nitrate synthesis of a ceramic-metal composite, 4
H Schmalzried (1961)
Radiographic investigation of cation distribution in spinel phasesZ Phys Chem, 28
Xuejiao Liu, Da Han, Hao Wu, X. Meng, F. Zeng, Z. Zhan (2013)
Mn1.5Co1.5O4−δ infiltrated yttria stabilized zirconia composite cathodes for intermediate-temperature solid oxide fuel cellsInternational Journal of Hydrogen Energy, 38
S. Amancherla, R. Banerjee, S. Banerjee, H. Fraser (2000)
Ordering in ternary B2 alloysInternational Journal of Refractory Metals & Hard Materials, 18
K. Leonard, V. Vasudevan (2000)
Phase equilibria and solid state transformations in Nb-rich Nb–Ti–Al intermetallic alloysIntermetallics, 8
J. Paterson, O. Krivanek (1990)
Elnes of 3d transition-metal oxides. II, Variations with oxidation state and crystal structureUltramicroscopy, 32
L. Allen (1993)
Electron energy loss spectroscopy in a crystalline environment using inner-shell ionizationUltramicroscopy, 48
H. Bordeneuve, S. Guillemet-Fritsch, A. Rousset, S. Schuurman, V. Poulain (2009)
Structure and electrical properties of single-phase cobalt manganese oxide spinels Mn3−xCoxO4 sintered classically and by spark plasma sintering (SPS)Journal of Solid State Chemistry, 182
Jingfa Li, S. Xiong, Xiaowei Li, Yitai Qian (2013)
A facile route to synthesize multiporous MnCo2O4 and CoMn2O4 spinel quasi-hollow spheres with improved lithium storage properties.Nanoscale, 5 5
T. Sawabe, T. Yano (2008)
Neutron irradiation effect on site distribution of cations in non-stoichiometric magnesium aluminate spinelJournal of Nuclear Materials, 373
L. Gambino, N. Magdefrau, M. Aindow (2015)
ALCHEMI Studies of Spinel Oxides for SOFC Interconnect Alloy CoatingsMicroscopy and Microanalysis, 21
H. Schmalzried (1961)
Röntgenographische Untersuchung der Kationenverteilung in SpinellphasenZeitschrift für Physikalische Chemie, 28
Z. Horita, S. Matsumura, T. Baba (1995)
General formulation for ALCHEMIUltramicroscopy, 58
R. Banerjee, S. Amancherla, S. Banerjee, H. Fraser (2002)
Modeling of site occupancies in B2 FeAl and NiAl alloys with ternary additionsActa Materialia, 50
I. Jones (2003)
Determining the locations of chemical species in ordered compounds: ALCHEMIAdvances in Imaging and Electron Physics, 125
E. Verwey, F. Boer, J. Santen (1948)
Cation Arrangement in SpinelsJournal of Chemical Physics, 16
R. Cooley, J. Reed (1972)
Equilibrium Cation Distribution in NiAl2O4, CuAl2O4, and ZnAl2O4 SpinelsJournal of the American Ceramic Society, 55
J. Sitter, A. Govaert, E. Grave, D. Chambaere (2010)
Mossbauer Spectroscopy as a Tool for the Investigation of Industrial Iron Ore SintersBulletin des Sociétés Chimiques Belges, 86
D. Hou, I. Jones, H. Fraser (1996)
The ordering tie-line method for sublattice occupancy in intermetallic compoundsPhilosophical Magazine, 74
A. Purwanto, A. Fajar, H. Mugirahardjo, J. Fergus, K. Wang (2010)
Cation distribution in spinel (Mn,Co,Cr)3O4at room temperatureJournal of Applied Crystallography, 43
N. Jiang, T. Rong, I. Jones, M. Aindow (1999)
On the Effect of Antiphase Domain Boundaries on ALCHEMIPhysica Status Solidi B-basic Solid State Physics, 214
N. Horr, S. Guillemet-Fritsch, A. Rousset, H. Bordeneuve, C. Tenailleau (2014)
Microstructure of single-phase cobalt and manganese oxide spinel Mn3−xCoxO4 ceramicsJournal of The European Ceramic Society, 34
E. Ríos, J. Gautier, G. Poillerat, P. Chartier (1998)
Mixed valency spinel oxides of transition metals and electrocatalysis: case of the MnxCo3−xO4 systemElectrochimica Acta, 44
H. O’Neill, A. Navrotsky (1983)
Simple spinels; crystallographic parameters, cation radii, lattice energies, and cation distributionAmerican Mineralogist, 68
S. Jain, K. Adiga, V. Verneker (1981)
A new approach to thermochemical calculations of condensed fuel-oxidizer mixturesCombustion and Flame, 40
M. Vakiv, O. Shpotyuk, O. Mrooz, I. Hadzaman (2001)
Controlled thermistor effect in the system CuxNi1–x–yCo2yMn2–yO4Journal of The European Ceramic Society, 21
G. Blasse (2014)
MAGNETIC PROPERTIES OF SOME OXIDES WITH SPINEL STRUCTURE
L. Gambino, N. Magdefrau, M. Aindow (2015)
Microstructural effects of the reduction step in reactive consolidation of manganese cobaltite coatings on Crofer 22 APUMaterials at High Temperatures, 32
H. Tan, J. Verbeeck, A. Abakumov, G. Tendeloo (2012)
Oxidation state and chemical shift investigation in transition metal oxides by EELSUltramicroscopy, 116
J. Spence, J. Taftø (1982)
ATOMIC SITE AND SPECIES DETERMINATION USING THE CHANNELING EFFECT IN ELECTRON DIFFRACTION.Scanning electron microscopy
Lei Chen, E. Sun, J. Yamanis, N. Magdefrau (2010)
Oxidation Kinetics of Mn1.5Co1.5O4-Coated Haynes 230 and Crofer 22 APU for Solid Oxide Fuel Cell InterconnectsJournal of The Electrochemical Society, 157
L. Allen, T. Josefsson, C. Rossouw (1994)
Interaction delocalization in characteristic X-ray emission from light elementsUltramicroscopy, 55
T. Rong, David Horspool, M. Aindow (2002)
Microstructure and mechanical behaviour of Nb–Al–V alloys with 10–25 at.% Al and 20–40 at.% V—II: mechanical behaviour and deformation mechanismsIntermetallics, 10
N. Magdefrau, Lei Chen, E. Sun, M. Aindow (2014)
The effect of Mn1.5Co1.5O4 coatings on the development of near surface microstructure for Haynes 230 oxidized at 800 °C in airSurface & Coatings Technology, 242
J. Spence, J. Taftø (1983)
ALCHEMI: a new technique for locating atoms in small crystalsJournal of Microscopy, 130
J. Taftø, J. Spence (1982)
Atomic site determination using the channeling effect in electron-induced x-ray emissionUltramicroscopy, 9
N. Magdefrau, Lei Chen, E. Sun, J. Yamanis, M. Aindow (2013)
Formation of spinel reaction layers in manganese cobaltite – coated Crofer22 APU for solid oxide fuel cell interconnectsJournal of Power Sources, 227
Hailiang Wang, Yuan Yang, Yongye Liang, G. Zheng, Yanguang Li, Yi Cui, H. Dai (2012)
Rechargeable Li–O2 batteries with a covalently coupled MnCo2O4–graphene hybrid as an oxygen cathode catalystEnergy and Environmental Science, 5
A. Navrotsky, O. Kleppa (1967)
The thermodynamics of cation distributions in simple spinelsJournal of Inorganic and Nuclear Chemistry, 29
A. Petric, H. Ling (2007)
Electrical Conductivity and Thermal Expansion of Spinels at Elevated TemperaturesJournal of the American Ceramic Society, 90
N. Jiang, D. Hou, I. Jones, H. Fraser (1999)
Optimizing the ALCHEMI techniquePhilosophical Magazine, 79
C. Kriessman, S. Harrison (1956)
CATION DISTRIBUTIONS IN FERROSPINESL, II. MAGNESIUM-MANGANESE FERRITES,
O. Krivanek, J. Paterson (1990)
Elnes of 3d transition-metal oxides: I. Variations across the periodic tableUltramicroscopy, 32
G Blasse (1964)
Crystal chemistry and some magnetic properties of mixed metal oxides with spinel structuresPhilips Res Rep Suppl, 3
P. Lavela, J. Tirado, Candela Vidal-Abarca (2007)
Sol–gel preparation of cobalt manganese mixed oxides for their use as electrode materials in lithium cellsElectrochimica Acta, 52
Z. Yang, Guanguang Xia, Xiao‐Hong Li, J. Stevenson (2007)
(Mn,Co)3O4 spinel coatings on ferritic stainless steels for SOFC interconnect applicationsInternational Journal of Hydrogen Energy, 32
P. Umadevi, C. Nagendra (2002)
Preparation and characterisation of transition metal oxide micro-thermistors and their application to immersed thermistor bolometer infrared detectorsSensors and Actuators A-physical, 96
D. Mcclure (1957)
The distribution of transition metal cations in spinelsJournal of Physics and Chemistry of Solids, 3
H. Bordeneuve, C. Tenailleau, S. Guillemet-Fritsch, Ronald Smith, E. Suard, A. Rousset (2010)
Structural variations and cation distributions in Mn3−xCoxO4 (0 ≤ x ≤ 3) dense ceramics using neutron diffraction dataSolid State Sciences, 12
R. Hill, J. Craig, G. Gibbs (1979)
Systematics of the spinel structure typePhysics and Chemistry of Minerals, 4
T. Soeda, S. Matsumura, C. Kinoshita, N. Zaluzec (2000)
Cation disordering in magnesium aluminate spinel crystals induced by electron or ion irradiationJournal of Nuclear Materials, 283
B. Lefez, P. Nkeng, J. Lopitaux, G. Poillerat (1996)
Characterization of cobaltite spinels by reflectance spectroscopyMaterials Research Bulletin, 31
TS Rong, DN Horspool, M Aindow (2002)
Microstructure and mechanical behaviour of Nb-Al-V Alloys with 10-25%Al and 20-40%V: I microstructural observationsIntermetallics, 10
E. Vila, R. Rojas, and Vidales, O. García-Martínez (1996)
Structural and Thermal Properties of the Tetragonal Cobalt Manganese Spinels MnxCo3-xO4 (1.4 < x < 2.0)Chemistry of Materials, 8
B. Boucher, R. Buhl, R. Bella, M. Perrin (1970)
Etude par des mesures de diffraction de neutrons et de magnétisme des propriétés cristallines et magnétiques de composés cubiques spinelles Co3-xMnxO4(0,6 ≤ x ≤ 1,2)Journal De Physique, 31
P. Joy, S. Date (2000)
Unusual magnetic hysteresis behavior of oxide spinel MnCo2O4Journal of Magnetism and Magnetic Materials, 210
The effects of Cr, Ni, and Fe substitution into manganese cobaltite (MCO) spinels are of great interest due to the roles that the diffusion of these cations play in reaction layer development during high temperature exposure of MCO-coated alloys. Here we report a study on a series of model Cr-, Ni-, and Fe-substituted MCO spinel ceramics produced by consolidation of combustion-synthesized oxide powders. The cation site occupancies in these samples have been studied by X-ray spectrometry-based Atom Location by CHanneling Enhanced MIcroanalysis (ALCHEMI) experiments in the transmission electron microscope, with the data being analyzed using the ordering tie-line approach. In Cr-substituted samples, the Cr ions lie on the octahedral B sites and the Co ions reside on the tetrahedral A sites with Mn occupying the remaining sites. In Ni-substituted samples, all of the Ni ions occupy the B sites and the Co and Mn ions tend to lie on A and B sites, respectively. In contrast to the Cr-substituted samples, there is some mixing of the Co and Mn ions on the two types of sites at lower Ni contents. In Fe-substituted samples with lower Fe contents, all of the Mn ions occupy the B sites, roughly equal proportions of Fe ions occupy the A and B sites, and Co ions fill the remaining sites. With increasing Fe content, the degree of order decreases which ultimately results in the High Fe sample exhibiting no channeling evidence for preferred site occupation. These ALCHEMI data could provide a useful insight into the role of cation sub-lattice site preference in the formation of reaction layers in MCO-coated stainless steels and superalloys.
Journal of Materials Science – Springer Journals
Published: Aug 7, 2015
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.