Z-Selective alkyne semi-hydrogenation catalysed by piano-stool N-heterocyclic carbene iron complexesElectronic supplementary information (ESI) available: Experimental details and time-conversion profiles. See DOI: 10.1039/c8cy00681d

Z-Selective alkyne semi-hydrogenation catalysed by piano-stool N-heterocyclic carbene iron... NHC iron(ii) piano-stool complexes catalyse the selective semi-hydrogenation of alkynes to alkenes using silanes as reducing agents. Aromatic terminal alkynes are converted to styrenes without over-reduction to ethylbenzene derivatives. Furthermore, internal aryl alkynes afford cis-alkenes with excellent Z-selectivity. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Catalysis Science & Technology Royal Society of Chemistry

Z-Selective alkyne semi-hydrogenation catalysed by piano-stool N-heterocyclic carbene iron complexesElectronic supplementary information (ESI) available: Experimental details and time-conversion profiles. See DOI: 10.1039/c8cy00681d

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Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
2044-4753
eISSN
2044-4761
D.O.I.
10.1039/c8cy00681d
Publisher site
See Article on Publisher Site

Abstract

NHC iron(ii) piano-stool complexes catalyse the selective semi-hydrogenation of alkynes to alkenes using silanes as reducing agents. Aromatic terminal alkynes are converted to styrenes without over-reduction to ethylbenzene derivatives. Furthermore, internal aryl alkynes afford cis-alkenes with excellent Z-selectivity.

Journal

Catalysis Science & TechnologyRoyal Society of Chemistry

Published: May 8, 2018

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