Polymorphism of Ag29(BDT)12(TPP)43 cluster: interactions of secondary ligands and their effect on solid state luminescenceElectronic supplementary information (ESI) available. See DOI: 10.1039/c8nr02629g

Polymorphism of Ag29(BDT)12(TPP)43 cluster: interactions of secondary ligands and their effect on... We present the first example of polymorphism (cubic & trigonal) in single crystals of an atomically precise monolayer protected cluster, Ag29(BDT)12(TPP)43. We demonstrate that CH interactions of the secondary ligands (TPP) are dominant in a cubic lattice compared to a trigonal lattice, resulting in a greater rigidity of the structure, which in turn, results in a higher luminescence efficiency in it. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Nanoscale Royal Society of Chemistry

Polymorphism of Ag29(BDT)12(TPP)43 cluster: interactions of secondary ligands and their effect on solid state luminescenceElectronic supplementary information (ESI) available. See DOI: 10.1039/c8nr02629g

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Publisher
The Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
2040-3364
D.O.I.
10.1039/c8nr02629g
Publisher site
See Article on Publisher Site

Abstract

We present the first example of polymorphism (cubic & trigonal) in single crystals of an atomically precise monolayer protected cluster, Ag29(BDT)12(TPP)43. We demonstrate that CH interactions of the secondary ligands (TPP) are dominant in a cubic lattice compared to a trigonal lattice, resulting in a greater rigidity of the structure, which in turn, results in a higher luminescence efficiency in it.

Journal

NanoscaleRoyal Society of Chemistry

Published: May 23, 2018

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