Heterogeneously catalyzed selective hydrogenation of amides to alcohols and aminesElectronic supplementary information (ESI) available: Details of catalysts' synthesis, and experimental procedures. See DOI: 10.1039/c8cy00112j

Heterogeneously catalyzed selective hydrogenation of amides to alcohols and aminesElectronic... We report the heterogeneously catalyzed hydrogenation of amides to form alcohols and amines. This CN bond cleavage reaction is catalyzed by silver on -alumina, proceeds smoothly in high yields and 100% selectivity, and is effective for both benzamides and aliphatic amides. This is in contrast to amide hydrogenation catalyzed by heterogeneous catalysts, which generally proceeds via CO bond cleavage. Recycling experiments show that the catalyst Ag/-Al2O3 can be easily recovered and regenerated without decrease in catalytic activity. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Catalysis Science & Technology Royal Society of Chemistry

Heterogeneously catalyzed selective hydrogenation of amides to alcohols and aminesElectronic supplementary information (ESI) available: Details of catalysts' synthesis, and experimental procedures. See DOI: 10.1039/c8cy00112j

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Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
2044-4753
eISSN
2044-4761
D.O.I.
10.1039/c8cy00112j
Publisher site
See Article on Publisher Site

Abstract

We report the heterogeneously catalyzed hydrogenation of amides to form alcohols and amines. This CN bond cleavage reaction is catalyzed by silver on -alumina, proceeds smoothly in high yields and 100% selectivity, and is effective for both benzamides and aliphatic amides. This is in contrast to amide hydrogenation catalyzed by heterogeneous catalysts, which generally proceeds via CO bond cleavage. Recycling experiments show that the catalyst Ag/-Al2O3 can be easily recovered and regenerated without decrease in catalytic activity.

Journal

Catalysis Science & TechnologyRoyal Society of Chemistry

Published: May 10, 2018

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