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Christophe Thomas, G. Süss-Fink (2003)
Ligand effects in the rhodium-catalyzed carbonylation of methanolCoordination Chemistry Reviews, 243
N. Yoneda, S. Kusano, M. Yasui, P. Pujadó, S. Wilcher (2001)
Recent advances in processes and catalysts for the production of acetic acidApplied Catalysis A-general, 221
R. Sowden, M. Sellin, N. Blasio, D. Cole-Hamilton (1999)
Carbonylation of methanol in supercritical CO2 catalysed by a supported rhodium complexChemical Communications
R. Kamai, K. Kamiya, K. Hashimoto, Shuji Nakanishi (2016)
Oxygen-Tolerant Electrodes with Platinum-Loaded Covalent Triazine Frameworks for the Hydrogen Oxidation Reaction.Angewandte Chemie, 55 42
G. Sunley, D. Watson (2000)
High productivity methanol carbonylation catalysis using iridiumCatalysis Today, 58
A. Bavykina, A. Olivos-Suarez, D. Osadchii, Rahul Valecha, R. Franz, M. Makkee, F. Kapteijn, J. Gascón (2017)
Facile Method for the Preparation of Covalent Triazine Framework coated Monoliths as Catalyst Support: Applications in C1 Catalysis.ACS applied materials & interfaces, 9 31
Xingang Li, Xiaoguang San, Yi Zhang, T. Ichii, M. Meng, Yisheng Tan, N. Tsubaki (2010)
Direct synthesis of ethanol from dimethyl ether and syngas over combined H-Mordenite and Cu/ZnO catalysts.ChemSusChem, 3 10
M. Jarrell, B. Gates (1975)
Methanol carbonylation catalyzed by a polymer-bound rhodium (I) complexJournal of Catalysis, 40
P. Saikia, P. Sarmah, B. Borah, L. Saikia, D. Dutta (2016)
Functionalized montmorillonite supported rhodium complexes: Efficient catalysts for carbonylation of methanolJournal of Molecular Catalysis A-chemical, 412
R. Palkovits, M. Antonietti, P. Kuhn, Arne Thomas, F. Schüth (2009)
Solid catalysts for the selective low-temperature oxidation of methane to methanol.Angewandte Chemie, 48 37
Z. Ren, Yuan Lyu, Feng Siquan, Xiangen Song, Yunjie Ding (2017)
A highly efficient single site Rh-POL-PPh3 catalyst for heterogeneous methanol carbonylationMolecular Catalysis, 442
A. Bavykina, H.-H. Mautscke, M. Makkee, F. Kapteijn, J. Gascón, F. Xamena (2017)
Base free transfer hydrogenation using a covalent triazine framework based catalystCrystEngComm, 19
A. Fulford, C. Hickey, P. Maitlis (1990)
Factors influencing the oxidative addition of iodomethane to [Rh(CO)2I2]-, the key step in methanol and methyl acetate carbonylationJournal of Organometallic Chemistry, 398
A. Bavykina, H.-H. Mautscke, M. Makkee, F. Kapteijn, J. Gascón, F. Xamena (1978)
Soils, plants and fertilizers, 8
A. Budiman, J. Nam, J. Park, Ryan Mukti, Tae-sun Chang, J. Bae, Myoung-Jae Choi (2016)
Review of Acetic Acid Synthesis from Various Feedstocks Through Different Catalytic ProcessesCatalysis Surveys from Asia, 20
P. Sudakar, Gunniya Gunasekar, I. Baek, Sungho Yoon (2016)
Recyclable and efficient heterogenized Rh and Ir catalysts for the transfer hydrogenation of carbonyl compounds in aqueous mediumGreen Chemistry, 18
Kwangho Park, Gunniya Gunasekar, N. Prakash, K. Jung, Sungho Yoon (2015)
A Highly Efficient Heterogenized Iridium Complex for the Catalytic Hydrogenation of Carbon Dioxide to Formate.ChemSusChem, 8 20
Anastasiya Bavykina, Maarten Goesten, F. Kapteijn, M. Makkee, Jorge Gascon (2015)
Efficient production of hydrogen from formic acid using a covalent triazine framework supported molecular catalyst.ChemSusChem, 8 5
A. Riisager, B. Jørgensen, P. Wasserscheid, R. Fehrmann (2006)
First application of supported ionic liquid phase (SILP) catalysis for continuous methanol carbonylation.Chemical communications, 9
Yue Wang, Yujun Zhao, Jing Lv, Xinbin Ma (2017)
Facile Synthesis of Cu@CeO2 and Its Catalytic Behavior for the Hydrogenation of Methyl Acetate to EthanolChemCatChem, 9
G. Flores-Escamilla, J. Fierro-González (2012)
Participation of linear methoxy species bonded to Ti4+ sites in the methanol carbonylation catalyzed by TiO2-supported rhodium: An infrared investigationJournal of Molecular Catalysis A-chemical, 359
Kazuyuki Iwase, Tatsuro Yoshioka, Shuji Nakanishi, K. Hashimoto, K. Kamiya (2015)
Copper-modified covalent triazine frameworks as non-noble-metal electrocatalysts for oxygen reduction.Angewandte Chemie, 54 38
S. Rajendiran, Prakash Natarajan, Sungho Yoon (2017)
A covalent triazine framework-based heterogenized Al–Co bimetallic catalyst for the ring-expansion carbonylation of epoxide to β-lactoneRSC Advances, 7
A. Haynes, B. Mann, G. Morris, P. Maitlis (1993)
Mechanistic studies on rhodium-catalyzed carbonylation reactions : spectroscopic detection and reactivity of a key intermediate, [MeRh(CO)2I3]-Journal of the American Chemical Society, 115
Tatsuro Yoshioka, Kazuyuki Iwase, Shuji Nakanishi, K. Hashimoto, K. Kamiya (2016)
Electrocatalytic Reduction of Nitrate to Nitrous Oxide by a Copper-Modified Covalent Triazine FrameworkJournal of Physical Chemistry C, 120
N. Blasio, E. Tempesti, A. Kaddouri, C. Mazzocchia, D. Cole-Hamilton (1998)
Activity and Stability of Two Polymer-Supported Rhodium-Based Catalysts for the Vapour Phase Carbonylation of MethanolJournal of Catalysis, 176
Fengbo Li, Bingfeng Chen, Zhijun Huang, Tao Lu, Yinggen Yuan, G. Yuan (2013)
Sustainable catalysts for methanol carbonylationGreen Chemistry, 15
S. Rajendiran, Kwangho Park, K. Lee, Sungho Yoon (2017)
Ionic-Liquid-Based Heterogeneous Covalent Triazine Framework Cobalt Catalyst for the Direct Synthesis of Methyl 3-Hydroxybutyrate from Propylene Oxide.Inorganic chemistry, 56 12
Lee Dingwall, A. Lee, Jason Lynam, K. Wilson, L. Olivi, Jon Deeley, S. Gaemers, G. Sunley (2012)
Bifunctional Organorhodium Solid Acid Catalysts for Methanol CarbonylationACS Catalysis, 2
Christina Standfest-Hauser, T. Lummerstorfer, R. Schmid, H. Hoffmann, K. Kirchner, M. Puchberger, A. Trzeciak, Ewa Mieczyńska, W. Tylus, J. Ziółkowski (2004)
Rhodium phosphine complexes immobilized on silica as active catalysts for 1-hexene hydroformylation and arene hydrogenationJournal of Molecular Catalysis A-chemical, 210
Xiumin Huang, Meng Ma, S. Miao, Yanping Zheng, Mingshu Chen, Wenjie Shen (2017)
Hydrogenation of methyl acetate to ethanol over a highly stable Cu/SiO2 catalyst: Reaction mechanism and structural evolutionApplied Catalysis A-general, 531
D. Rasmussen, J. Christensen, B. Temel, F. Studt, P. Moses, J. Rossmeisl, A. Riisager, A. Jensen (2017)
Reaction mechanism of dimethyl ether carbonylation to methyl acetate over mordenite: a combined DFT/experimental studyCatalysis Science & Technology, 7
A. Bavykina, E. Rozhko, Maarten Goesten, T. Wezendonk, B. Seoane, F. Kapteijn, M. Makkee, J. Gascón (2016)
Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic AcidChemCatChem, 8
Onur Buyukcakir, Sang Je, S. Talapaneni, Daeok Kim, Ali Coskun (2017)
Charged Covalent Triazine Frameworks for CO2 Capture and Conversion.ACS applied materials & interfaces, 9 8
Gunniya Gunasekar, Kwangho Park, V. Ganesan, K. Lee, Nak-Kyoon Kim, K. Jung, Sungho Yoon (2017)
A Covalent Triazine Framework, Functionalized with Ir/N-Heterocyclic Carbene Sites, for the Efficient Hydrogenation of CO2 to FormateChemistry of Materials, 29
Xiaoguang San, Yi Zhang, Wenjie Shen, N. Tsubaki (2009)
New Synthesis Method of Ethanol from Dimethyl Ether with a Synergic Effect between the Zeolite Catalyst and Metallic CatalystEnergy & Fuels, 23
M. Román-Martínez, J. Díaz-Auñón, C. Lecea, H. Alper (2004)
Rhodium-diphosphine complex bound to activated carbon: An effective catalyst for the hydroformylation of 1-octeneJournal of Molecular Catalysis A-chemical, 213
Yoneda Noriyuki, Minamide Takeshi, W. Joe, Spehlmann Ben (1999)
The chiyoda/uop acetica™ process: A novel acetic acid technologyStudies in Surface Science and Catalysis, 121
Seungjun Choo, Youngsoon Um, S. Han, H. Woo (2016)
Engineering of Corynebacterium glutamicum to utilize methyl acetate, a potential feedstock derived by carbonylation of methanol with CO.Journal of biotechnology, 224
Shufeng Zhang, Cun-Yue Guo, Qingli Qian, G. Yuan (2008)
Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalystCatalysis Communications, 9
Mario Soorholtz, L. Jones, D. Samuelis, C. Weidenthaler, Robin White, M. Titirici, D. Cullen, T. Zimmermann, M. Antonietti, J. Maier, R. Palkovits, B. Chmelka, F. Schüth (2016)
Local Platinum Environments in a Solid Analogue of the Molecular Periana CatalystACS Catalysis, 6
N. Blasio, M. Wright, E. Tempesti, C. Mazzocchia, D. Cole-Hamilton (1998)
The relative importance of heterogeneous and homogeneous methanol carbonylation using supported rhodium catalysts in the liquid phaseJournal of Organometallic Chemistry, 551
J. Nam, A. Kim, Da Kim, Tae-sun Chang, B. Kim, J. Bae (2017)
Novel heterogeneous Rh-incorporated graphitic-carbon nitride for liquid-phase carbonylation of methanol to acetic acidCatalysis Communications, 99
Kwangho Park, K. Lee, Hyunuk Kim, V. Ganesan, Kanghee Cho, S. Jeong, Sungho Yoon (2017)
Preparation of covalent triazine frameworks with imidazolium cations embedded in basic sites and their application for CO2 captureJournal of Materials Chemistry, 5
Direct carbonylation of methanol into methyl acetate and acetic acid using Rh-based heterogeneous catalysts is of great interest due to their effective levels of activity and stability. Here, a Rh-based molecular catalyst heterogenized on a charged 1,3-bis(pyridyl)imidazolium-based covalent triazine framework (Rh-bpim-CTF) was synthesized and characterized to have a single-site distribution of metal molecular species throughout the support by its ligation to abundant N atom sites. Methanol carbonylation was performed using the Rh-bpim-CTF catalyst in a plug-flow reaction in the gas phase, affording a turnover frequency of up to 3693 h−1 and a productivity of 218.9 mol kg−1 h−1 for acetyl products with high stability.
Catalysis Science & Technology – Royal Society of Chemistry
Published: Jun 5, 2018
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