Development of functional black phosphorus nanosheets with remarkable catalytic and antibacterial performanceElectronic supplementary information (ESI) available: Additional AFM, TEM, SEM, XPS, EDS, UV-vis, Raman and ICP-AES characterization studies, detailed catalytic analysis of x-AuNPs/BPNs hybrids, and the varied antibacterial performance of AuNPs/BPNs and AuNPs/C3N4 hybrids; SEM image of E. coli treated with BPNs and AuNPs/BPNs hybrids. See DOI: 10.1039/c8nr01715h

Development of functional black phosphorus nanosheets with remarkable catalytic and antibacterial... Highly dispersed 2D-nanostructured ultrathin black phosphorus nanosheets (BPNs)-integrated Au nanoparticles (AuNPs) hybrids were constructed in situ through a facile and environmentally friendly strategy. No additional reductants, surfactants, or polymer templates were introduced during this green and convenient synthesis process. The resulting AuNPs/BPNs nanohybrids were characterized by UV-vis, Raman spectroscopy, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasmaatomic emission spectroscopy (ICP-AES). The content of BPNs plays an essential role in modulating the morphologies and chemical states of AuNPs/BPNs hybrids, which have been investigated systematically and are discussed in detail. As high-density ultrasmall AuNPs are properly stabilized and accommodated without passivation by the surrounding ultrathin BPNs, the resulting AuNPs/BPNs hybrids exhibit excellent catalytic/antibacterial properties and long-term stabilities, benefiting from a possible synergistic enhancement effect between AuNPs and BPNs constructs. This simple, mild and environmentally benign strategy could be generalized to the preparation of other metal- or metal oxide-doped complexes and holds great promise for potential catalytic, bioanalytical and biomedical applications. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Nanoscale Royal Society of Chemistry

Development of functional black phosphorus nanosheets with remarkable catalytic and antibacterial performanceElectronic supplementary information (ESI) available: Additional AFM, TEM, SEM, XPS, EDS, UV-vis, Raman and ICP-AES characterization studies, detailed catalytic analysis of x-AuNPs/BPNs hybrids, and the varied antibacterial performance of AuNPs/BPNs and AuNPs/C3N4 hybrids; SEM image of E. coli treated with BPNs and AuNPs/BPNs hybrids. See DOI: 10.1039/c8nr01715h

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Publisher
The Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
2040-3364
D.O.I.
10.1039/c8nr01715h
Publisher site
See Article on Publisher Site

Abstract

Highly dispersed 2D-nanostructured ultrathin black phosphorus nanosheets (BPNs)-integrated Au nanoparticles (AuNPs) hybrids were constructed in situ through a facile and environmentally friendly strategy. No additional reductants, surfactants, or polymer templates were introduced during this green and convenient synthesis process. The resulting AuNPs/BPNs nanohybrids were characterized by UV-vis, Raman spectroscopy, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasmaatomic emission spectroscopy (ICP-AES). The content of BPNs plays an essential role in modulating the morphologies and chemical states of AuNPs/BPNs hybrids, which have been investigated systematically and are discussed in detail. As high-density ultrasmall AuNPs are properly stabilized and accommodated without passivation by the surrounding ultrathin BPNs, the resulting AuNPs/BPNs hybrids exhibit excellent catalytic/antibacterial properties and long-term stabilities, benefiting from a possible synergistic enhancement effect between AuNPs and BPNs constructs. This simple, mild and environmentally benign strategy could be generalized to the preparation of other metal- or metal oxide-doped complexes and holds great promise for potential catalytic, bioanalytical and biomedical applications.

Journal

NanoscaleRoyal Society of Chemistry

Published: May 24, 2018

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