Comment on Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al) by A. Perea-Cachero, E. Romero, C. Tllez and J. Coronas, CrystEngComm, 2018, 20, 402Electronic supplementary information (ESI) available: Synthesis procedures, indexing of the MIL-53DMF pattern, IR spectra and REM micrographs. See DOI: 10.1039/c8ce00398j

Comment on Insight into the reversible structural crystalline-state transformation from... In a recently published communication (CrystEngComm, 2018, 20, 402406), Perea-Cachero et al. stated that the topologically isomeric metalorganic frameworks MIL-53(Al) and MIL-68(Al) could be reversibly transformed into each other. However, the suggested synthesis procedure for MIL-68 indeed resulted in MIL-53 with DMF entrapped inside of the pores. The collected PXRD pattern of MIL-53DMF was then inadvertently assigned to the MIL-68 structure. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png CrystEngComm Royal Society of Chemistry

Comment on Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al) by A. Perea-Cachero, E. Romero, C. Tllez and J. Coronas, CrystEngComm, 2018, 20, 402Electronic supplementary information (ESI) available: Synthesis procedures, indexing of the MIL-53DMF pattern, IR spectra and REM micrographs. See DOI: 10.1039/c8ce00398j

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Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
1466-8033
D.O.I.
10.1039/c8ce00398j
Publisher site
See Article on Publisher Site

Abstract

In a recently published communication (CrystEngComm, 2018, 20, 402406), Perea-Cachero et al. stated that the topologically isomeric metalorganic frameworks MIL-53(Al) and MIL-68(Al) could be reversibly transformed into each other. However, the suggested synthesis procedure for MIL-68 indeed resulted in MIL-53 with DMF entrapped inside of the pores. The collected PXRD pattern of MIL-53DMF was then inadvertently assigned to the MIL-68 structure.

Journal

CrystEngCommRoyal Society of Chemistry

Published: May 23, 2018

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