A rare example of a compact heteroleptic cyclometalated iridium(iii) complex demonstrating well-separated dual emissionElectronic supplementary information (ESI) available. CCDC 1578517, 1539312 and 1538647. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt01336e

A rare example of a compact heteroleptic cyclometalated iridium(iii) complex demonstrating... A series of [Ir(C^N)2(NN)][PF6] complexes in which NN is 5-(4-ethynylphenyl)-2,2-bipyridine has been synthesized and characterized by spectroscopic methods. All novel complexes exhibit unique singlettriplet dual emission in solution with two well-separated emission bands. The mechanism of dual emission has been elucidated on the basis of experimental data and confirmed by TDDFT calculations. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Dalton Transactions Royal Society of Chemistry

A rare example of a compact heteroleptic cyclometalated iridium(iii) complex demonstrating well-separated dual emissionElectronic supplementary information (ESI) available. CCDC 1578517, 1539312 and 1538647. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt01336e

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Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
1477-9226
eISSN
1477-9234
D.O.I.
10.1039/c8dt01336e
Publisher site
See Article on Publisher Site

Abstract

A series of [Ir(C^N)2(NN)][PF6] complexes in which NN is 5-(4-ethynylphenyl)-2,2-bipyridine has been synthesized and characterized by spectroscopic methods. All novel complexes exhibit unique singlettriplet dual emission in solution with two well-separated emission bands. The mechanism of dual emission has been elucidated on the basis of experimental data and confirmed by TDDFT calculations.

Journal

Dalton TransactionsRoyal Society of Chemistry

Published: May 23, 2018

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