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P. Lucena, J. Vadillo, J. Laserna (1999)
Mapping of platinum group metals in automotive exhaust three-way catalysts using laser-induced breakdown spectrometry.Analytical chemistry, 71 19
M. Rokosz, A. Chen, C. Lowe-Ma, A. Kucherov, D. Benson, M. Peck, R. McCabe (2001)
Characterization of phosphorus-poisoned automotive exhaust catalystsApplied Catalysis B-environmental, 33
R. Farrauto, R. Heck (1999)
Catalytic converters: state of the art and perspectivesCatalysis Today, 51
P. Lucena, J. Vadillo, J. Laserna (2001)
Compositional Mapping of Poisoning Elements in Automobile Three-Way Catalytic Converters by Using Laser-Induced Breakdown SpectrometryApplied Spectroscopy, 55
F. Zereini, F. Alt (2000)
Anthropogenic Platinum-Group Element Emissions
P. Lucena, J. Laserna (2001)
Three-dimensional distribution analysis of platinum, palladium and rhodium in auto catalytic converters using imaging-mode laser-induced breakdown spectrometrySpectrochimica Acta Part B: Atomic Spectroscopy, 56
Laser-induced plasma spectrometry was used as a procedure for the comparative study of diesel-engine exhaust converters. Three-dimensional images were obtained and compared from “0 km” and “80 000 km” converters to generate semi-quantitative chemical images of the Pt load and of the poisoning elements P and Zn. The data revealed that a significant progressive depletion of Pt occurred from the converter region closest to the engine to the outer part of the catalyst. Deactivant elements were deposited along the full catalyst on usage for 80 000 km.
Journal of Analytical Atomic Spectroscopy – Royal Society of Chemistry
Published: Mar 20, 2002
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