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- Publisher
- Royal Society of Chemistry
- Copyright
- This journal is © The Royal Society of Chemistry
- ISSN
- 2044-4753
- eISSN
- 2044-4761
- DOI
- 10.1039/c4cy01604a
- Publisher site
- See Article on Publisher Site
Abstract
Six compounds of the type (CpMo(CO) 3 R) (R = Cl ( 1 ), CH 3 ( 2 ), CF 3 ( 3 )) and (CpMo(O 2 )(O)R) (R = Cl ( 4 ), CH 3 ( 5 ), CF 3 ( 6 ) (Cp = η 5 -cyclopentadienyl)) have been synthesised and characterised. The crystal structures of (CpMo(CO) 3 CF 3 ) and (CpMo(O 2 )(O)CF 3 ) are compared to their literature known chloro and methyl derivatives. The influence of the groups R on the performance as epoxidation catalysts is examined. DFT calculations, IR-spectroscopy and X-ray crystallography help to explain differences in reactivity and enable a rational design of active molybdenum tricarbonyl and oxo-peroxo complexes.
Journal
Catalysis Science & Technology – Royal Society of Chemistry
Published: Jan 15, 2015