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A. Blake, E. Pasteur, G. Reid, M. Schröder (1991)
Mercury thioether chemistry: The synthesis and X-ray crystal structure of [Hg([15]aneS5](PF6)2Polyhedron, 10
Gajendrasingh Ingle, M. Makowska-Grzyska, Ewa Szajna-Fuller, I. Sen, J. Price, A. Arif, L. Berreau (2007)
Influence of the chelate ligand structure on the amide methanolysis reactivity of mononuclear zinc complexes.Inorganic chemistry, 46 4
Russell Allred, S. Huefner, K. Rudzka, A. Arif, L. Berreau (2007)
A cadmium hydroxide complex of a N3S-donor ligand containing two hydrogen bond donors: synthesis, characterization, and CO2 reactivity.Dalton transactions, 3
D. Bebout, D. Ehmann, and Trinidad, K. Crahan, Margaret and, D. Parrish (1997)
Preparation of Mercury(II) Complexes of Tris[(2-pyridyl)methyl]amine and Characterization by X-ray Crystallography and NMR SpectroscopyInorganic Chemistry, 36
Jeffrey Wright, M. Natan, F. MacDonnell, D. Ralston, T. O’Halloran (2007)
Mercury(II)-thiolate chemistry and the mechanism of the heavy metal biosensor MerRProgress in Inorganic Chemistry, 38
Russell Allred, L. McAlexander, A. Arif, L. Berreau (2002)
Chemistry of a binuclear cadmium(II) hydroxide complex: formation from water, CO(2) reactivity, and comparison to a zinc analog.Inorganic chemistry, 41 25
B. Aylett (1975)
The chemistry of zinc, cadmium and mercury
Sungho Yoon, Evan Miller, Qi-Wen He, P. Do, Christopher Chang (2007)
A bright and specific fluorescent sensor for mercury in water, cells, and tissue.Angewandte Chemie, 46 35
G. Parkin (2004)
Synthetic analogues relevant to the structure and function of zinc enzymes.Chemical reviews, 104 2
(2022)
Purification of Laboratory Chemicals
D. Bebout, S. Berry (2006)
Probing mercury complex speciation with multinuclear NMR
L. Utschig, J. Bryson, T. O’Halloran (1995)
Mercury-199 NMR of the metal receptor site in MerR and its protein-DNA complex.Science, 268 5209
Dewain Garner, Sarah Fitch, L. McAlexander, Li Bezold, A. Arif, L. Berreau (2002)
Mononuclear nitrogen/sulfur-ligated zinc methoxide and hydroxide complexes: investigating ligand effects on the hydrolytic stability of zinc alkoxide species.Journal of the American Chemical Society, 124 34
D. Bebout, Wei Lai, Sarah Stamps, S. Berry, R. Butcher (2007)
Zinc triad metal ion complexes of NN′S ligand N-(2-pyridylmethyl)-N-(2-(methylthio)ethyl)amineMain Group Chemistry, 6
Yan Zhao, Zhenqi Zhong (2006)
Tuning the sensitivity of a foldamer-based mercury sensor by its folding energy.Journal of the American Chemical Society, 128 31
P. Barak, P. Helmke (1993)
The Chemistry of Zinc
Yan Xu, Liang Feng, P. Jeffrey, Yigong Shi, F. Morel (2008)
Structure and metal exchange in the cadmium carbonic anhydrase of marine diatomsNature, 452
Elizabeth Nolan, S. Lippard (2003)
A "turn-on" fluorescent sensor for the selective detection of mercuric ion in aqueous media.Journal of the American Chemical Society, 125 47
D. Grdenić (1965)
The structural chemistry of mercuryQuarterly Reviews, Chemical Society, 19
Lok Neupane, P. Thirupathi, Sujung Jang, M. Jang, Jung Kim, Keun-Hyeung Lee (2011)
Highly selectively monitoring heavy and transition metal ions by a fluorescent sensor based on dipeptide.Talanta, 85 3
D. Bebout, James II, K. Crahan, M. Kastner, D. Parrish (1998)
Correlation of a Solution-State Conformational Change between Mercuric Chloride Complexes of Tris[(2-(6-methylpyridyl))methyl]amine with X-ray Crystallographic Structures.Inorganic chemistry, 37 18
D. Bebout, Wei Lai, Sarah Stamps, S. Berry, R. Butcher (2008)
Bis-tridentate Chelates of an Asymmetric Ligand: X-ray Structures and Solution NMR Characterization of Divalent Zinc Triad Metal Ion Complexes of N-(2-pyridylmethyl)-N-(2-(methylthio)ethyl)amine.Polyhedron, 27 6
Jianjun Du, Jiangli Fan, Xiaojun Peng, Honglin Li, Jingyun Wang, Shiguo Sun (2008)
Highly Selective and Anions Controlled Fluorescent Sensor for Hg2+ in Aqueous EnvironmentJournal of Fluorescence, 18
Huajun Dai, Fei Liu, Qianqian Gao, Tianhua Fu, Xingming Kou (2011)
A highly selective fluorescent sensor for mercury ion (II) based on azathia-crown ether possessing a dansyl moiety.Luminescence : the journal of biological and chemical luminescence, 26 6
S. Berry, D. Bebout, R. Butcher (2005)
Solid-state and solution-state coordination chemistry of the zinc triad with the mixed N,S donor ligand bis(2-methylpyridyl) sulfide.Inorganic chemistry, 44 1
M. Makowska-Grzyska, Kelly Doyle, Russell Allred, A. Arif, D. Bebout, L. Berreau (2005)
Structural, Spectroscopic, and Reactivity Properties of N2S2(thioether)‐O(amide)‐Ligated HgII Complexes: The First Examples of HgII‐Mediated Amide CleavageEuropean Journal of Inorganic Chemistry, 2005
Juan Mareque‐Rivas, R. Prabaharan, S. Parsons (2004)
Quantifying the relative contribution of hydrogen bonding and hydrophobic environments, and coordinating groups, in the zinc(II)-water acidity by synthetic modelling chemistry.Dalton transactions, 10
Junhai Huang, Yufang Xu, X. Qian (2009)
A rhodamine-based Hg2+ sensor with high selectivity and sensitivity in aqueous solution: a NS2-containing receptor.The Journal of organic chemistry, 74 5
Russell Allred, A. Arif, L. Berreau (2002)
A binuclear cadmium(II) hydroxide complex and its CO2 reaction productJournal of The Chemical Society-dalton Transactions
Russell Allred, Kelly Doyle, A. Arif, L. Berreau (2006)
Solvent effects on the structural and formyl substrate reactivity properties of a nitrogen/sulfur-ligated zinc hydroxide complex.Inorganic chemistry, 45 10
E. Szajna, M. Makowska-Grzyska, Chad Wasden, A. Arif, L. Berreau (2005)
A deprotonated intermediate in the amide methanolysis reaction of an N4O-ligated mononuclear zinc complex.Inorganic chemistry, 44 21
D. Bebout, Anne DeLanoy, D. Ehmann, M. Kastner, D. Parrish, R. Butcher (1998)
Characterization of Mercury(II) Complexes of Bis((2-pyridyl)methyl)amine by X-ray Crystallography and NMR SpectroscopyInorganic Chemistry, 37
Mi-Hwa Yang, C. Lohani, Hyeongjin Cho, Keun-Hyeung Lee (2011)
A methionine-based turn-on chemical sensor for selectively monitoring Hg2+ ions in 100% aqueous solution.Organic & biomolecular chemistry, 9 7
Ryan Shook, A. Borovik (2008)
The effects of hydrogen bonds on metal-mediated O2 activation and related processes.Chemical communications, 46
Tao Chen, Weiping Zhu, Yufang Xu, Shenyi Zhang, Xiaojun Zhang, X. Qian (2010)
A thioether-rich crown-based highly selective fluorescent sensor for Hg(2+) and Ag(+) in aqueous solution.Dalton transactions, 39 5
D. Bebout, Sarah Stokes, R. Butcher (1999)
Comparison of Heteronuclear Coupling Constants for Isostructural Nitrogen Coordination Compounds of (111/113)Cd and (199)Hg.Inorganic chemistry, 38 6
Yan Zhao, Zhenqi Zhong (2006)
Detection of Hg2+ in aqueous solutions with a foldamer-based fluorescent sensor modulated by surfactant micelles.Organic letters, 8 21
H. Pieters, J. Creyghton (1951)
Safety in the chemical laboratory
F. Cotton (1999)
Advanced Inorganic Chemistry
D. Bebout, James II, K. Crahan, Edith Bowers, R. Butcher (2002)
Sterically demanding multidentate ligand tris[(2-(6-methylpyridyl))methyl]amine slows exchange and enhances solution state ligand proton NMR coupling to (199)Hg(II).Inorganic chemistry, 41 9
Wei Lai, S. Berry, D. Bebout, R. Butcher (2006)
Investigation of group 12 metal complexes with a tridentate SNS ligand by X-ray crystallography and 1H NMR spectroscopy.Inorganic chemistry, 45 2
D. Bebout, M. Garland, Geoffrey Murphy, Edith Bowers, C. Abelt, R. Butcher (2003)
Investigation of the mercury(II) coordination chemistry of tris[(1-methylimidazol-2-yl)methyl]amine by X-ray crystallography and NMRDalton Transactions
A. Borovik (2005)
Bioinspired hydrogen bond motifs in ligand design: the role of noncovalent interactions in metal ion mediated activation of dioxygen.Accounts of chemical research, 38 1
D. Bebout, James II, Elizabeth Shumann, J. Viehweg, M. Kastner, D. Parrish, Steven Baldwin (2003)
Caging the mercurous ion: a tetradentate tripodal nitrogen ligand enhances stability and J(1H199Hg)Journal of Chemical Crystallography, 33
Ewa Szajna-Fuller, Gajendrasingh Ingle, R. Watkins, A. Arif, L. Berreau (2007)
Amide hydrolysis reactivity of a N4O-ligated zinc complex: comparison of kinetic and themodynamic parameters with those of the corresponding amide methanolysis reaction.Inorganic chemistry, 46 7
L. Berreau (2006)
Bioinorganic Chemistry of Group 12 Complexes Supported by Tetradentate Tripodal Ligands Having Internal Hydrogen‐Bond DonorsEuropean Journal of Inorganic Chemistry, 2006
L. Berreau, Russell Allred, M. Makowska-Grzyska, A. Arif (2000)
Synthesis and structure of a nitrogen/sulfur-ligated zinc hydroxide complexChemical Communications
M. Sobhia, K. Panneerselvam, K. Chacko, I. Suh, E. Weber, C. Reutel (1992)
Crystal structure of the 2:1 complex of mercury(II) chloride with trithiapyridino-12-crown-4 having unusual mercury coordinationInorganica Chimica Acta, 194
F. Cecconi, C. Ghilardi, S. Midollini, A. Orlandini (1998)
Synthesis and X-ray structure of the thioethereal mercury(II) complex [N(CH2CH2SCHMe2)3HgCl]2(Hg2Cl6)Inorganica Chimica Acta, 269
P. Pallavicini, Y. Diaz-Fernandez, F. Foti, C. Mangano, S. Patroni (2007)
Fluorescent sensors for Hg(2+) in micelles: a new approach that transforms an ON-OFF into an OFF-ON response as a function of the lipophilicity of the receptor.Chemistry, 13 1
L. Praveen, V. Ganga, R. Thirumalai, T. Sreeja, M. Reddy, R. Varma (2007)
A new Hg(2+) -selective fluorescent sensor based on a 1,3-alternate thiacalix[4]arene anchored with four 8-quinolinoloxy groups.Inorganic chemistry, 46 16
J. Iggo (1999)
NMR spectroscopy in inorganic chemistry
L. Berreau, †. Makowska-Grzyska, A. Arif (2000)
Amide Alcoholysis in Mononuclear Zinc and Cadmium Complexes Ligated by Thioether Sulfur and Nitrogen DonorsInorganic Chemistry, 39
Bernd Wrackmeyer, Rosalinda Contreras (2010)
199Hg NMR ParametersChemInform, 24
Admixture of the chelate ligand bmnpa (N,N-bis(2-methylthio)ethyl-N-((6-neopentylamino-2-pyridyl)methyl)amine) with an equimolar amount of Hg(ClO4)2·3H2O in CH3OH/CH2Cl2, followed by recrystallization from CH3CN/Et2O, yielded the Hg(II) perchlorate complex ((bmnpa)Hg(ClO4)2) (1). Addition of an equimolar amount of Me4NOH·5H2O to a CH3CN solution of 1, followed by recrystallization from CH3OH/Et2O, yielded the dinuclear Hg2 2+ complex ((bmnpaHg)2)(ClO4)2 (4). X-ray crystallographic characterization of 1·0.5CH3CN revealed a mononuclear structure having a primary coordination number of two with a distorted linear geometry, and four secondary bonds for an effective coordination number of six. The 1 H NMR spectrum of 1 in CD3CN shows distinctive 3 J199Hg-1H coupling in the benzylic -CH2- and thioether -SCH3 resonances. Complex 4·CH3OH exhibits a structure in the solid state wherein each mercury center of the Hg2 2+ ion displays thioether coordination and a distorted tetrahedral geometry. Complex 4 is the first dimercurous complex for which J199Hg-1H coupling involving a -SCH3 appendage is reported.
Main Group Chemistry – IOS Press
Published: Jan 1, 2012
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