Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

The crystal structure of lithium fluoroantimonate(V)

The crystal structure of lithium fluoroantimonate(V) <h2>Acta Crystallographica</h2><h3></h3><h3>0365-110X</h3> <h2>research papers</h2> Volume 15 Part 11 Pages 1098-1101 November 1962 <h2>The crystal structure of lithium fluoroantimonate(V)</h2> J. H. Burns 1098 Acta Cryst. (1962). 15, 1098 The Crystal Structure of Lithium Fluoroantimonate(V) BY JOH~ H. BUR~S Reactor Chemistry Division, Oak Ridge National Laboratory,* Oak Ridge, Tennessee, U.S.A. (Received 18 December 1961 arut in revised form 13 February 1962) The crystal structure of LiSbF6 has been determine(t by single-crystal counting techniques and least-squares refinement. The unit cell is rhombohedral, R3, with a = 5.43 A, ~ = 56° 58' and c<)ntains one formula weight. The fluorine atoms form regular octahedra about the antimony and about the lithium atoms at distances of 1.88_+0.02 and 2.03_+0.02 z~, respectively. The structure may be described as a rhombohedral distortion of the cubic NaSbF6 arrangement. Introduction The structures of compounds with the formula RSbF6 have been reported for R+ equal to Na+ (Schrewelius, 1938); Ag+ (Bode, 1951); K+ (Bode & Voss, 1951); and Tl+, Rb+, NH~~ and Cs+ (Schrewelius, 1942). The arrangement of R+ and SbF;- ions in these crystals is of two types: NaC1 and CsC1 (distorted). Cox (1956) has pointed out that those fluoroantimonatcs(V) having R+ within a certain size range http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica International Union of Crystallography

The crystal structure of lithium fluoroantimonate(V)

Acta Crystallographica , Volume 15 (11): 1098 – Nov 10, 1962

The crystal structure of lithium fluoroantimonate(V)

Acta Crystallographica , Volume 15 (11): 1098 – Nov 10, 1962

Abstract

<h2>Acta Crystallographica</h2><h3></h3><h3>0365-110X</h3> <h2>research papers</h2> Volume 15 Part 11 Pages 1098-1101 November 1962 <h2>The crystal structure of lithium fluoroantimonate(V)</h2> J. H. Burns 1098 Acta Cryst. (1962). 15, 1098 The Crystal Structure of Lithium Fluoroantimonate(V) BY JOH~ H. BUR~S Reactor Chemistry Division, Oak Ridge National Laboratory,* Oak Ridge, Tennessee, U.S.A. (Received 18 December 1961 arut in revised form 13 February 1962) The crystal structure of LiSbF6 has been determine(t by single-crystal counting techniques and least-squares refinement. The unit cell is rhombohedral, R3, with a = 5.43 A, ~ = 56° 58' and c<)ntains one formula weight. The fluorine atoms form regular octahedra about the antimony and about the lithium atoms at distances of 1.88_+0.02 and 2.03_+0.02 z~, respectively. The structure may be described as a rhombohedral distortion of the cubic NaSbF6 arrangement. Introduction The structures of compounds with the formula RSbF6 have been reported for R+ equal to Na+ (Schrewelius, 1938); Ag+ (Bode, 1951); K+ (Bode & Voss, 1951); and Tl+, Rb+, NH~~ and Cs+ (Schrewelius, 1942). The arrangement of R+ and SbF;- ions in these crystals is of two types: NaC1 and CsC1 (distorted). Cox (1956) has pointed out that those fluoroantimonatcs(V) having R+ within a certain size range

Loading next page...
 
/lp/international-union-of-crystallography/the-crystal-structure-of-lithium-fluoroantimonate-v-8835KWzcqr

References

References for this paper are not available at this time. We will be adding them shortly, thank you for your patience.

Publisher
International Union of Crystallography
Copyright
Copyright (c) 1962 International Union of Crystallography
ISSN
0365-110X
DOI
10.1107/S0365110X62002935
Publisher site
See Article on Publisher Site

Abstract

<h2>Acta Crystallographica</h2><h3></h3><h3>0365-110X</h3> <h2>research papers</h2> Volume 15 Part 11 Pages 1098-1101 November 1962 <h2>The crystal structure of lithium fluoroantimonate(V)</h2> J. H. Burns 1098 Acta Cryst. (1962). 15, 1098 The Crystal Structure of Lithium Fluoroantimonate(V) BY JOH~ H. BUR~S Reactor Chemistry Division, Oak Ridge National Laboratory,* Oak Ridge, Tennessee, U.S.A. (Received 18 December 1961 arut in revised form 13 February 1962) The crystal structure of LiSbF6 has been determine(t by single-crystal counting techniques and least-squares refinement. The unit cell is rhombohedral, R3, with a = 5.43 A, ~ = 56° 58' and c<)ntains one formula weight. The fluorine atoms form regular octahedra about the antimony and about the lithium atoms at distances of 1.88_+0.02 and 2.03_+0.02 z~, respectively. The structure may be described as a rhombohedral distortion of the cubic NaSbF6 arrangement. Introduction The structures of compounds with the formula RSbF6 have been reported for R+ equal to Na+ (Schrewelius, 1938); Ag+ (Bode, 1951); K+ (Bode & Voss, 1951); and Tl+, Rb+, NH~~ and Cs+ (Schrewelius, 1942). The arrangement of R+ and SbF;- ions in these crystals is of two types: NaC1 and CsC1 (distorted). Cox (1956) has pointed out that those fluoroantimonatcs(V) having R+ within a certain size range

Journal

Acta CrystallographicaInternational Union of Crystallography

Published: Nov 10, 1962

There are no references for this article.