Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

The crystal and molecular structure of symmetrical cedrone, a dimeric oxidation product of trimethylphloroglucinol

The crystal and molecular structure of symmetrical cedrone, a dimeric oxidation product of... <h2>Acta Crystallographica Section B</h2><h3>Structural Crystallography and Crystal Chemistry</h3><h3>0567-7408</h3> <h2>research papers</h2> Volume 28 Part 1 Pages 298-304 January 1972 <h2>The crystal and molecular structure of symmetrical cedrone, a dimeric oxidation product of trimethylphloroglucinol</h2> J. A. Beisler and J. V. Silverton Acta Cryst. (1972). B28, 298 The Crystal and Molecular Structure of Symmetrical Cedrone, a Dimeric Oxidation Product of Trimethylphloroglucinol BY J. A. BEISLER The National Institute of Arthritis and Metabolic Diseases AND J. V. SILVERTON The National Heart and Lung Institute, Bethesda, Maryland 20014, U.S.A. (Received 29 January 1971) Symmetrical cedrone, C1sH2006, obtained by dimerization of trimethylphloroglucinol has been shown to be a centrosymmetric pentacyclic structure in the crystal of its dimethylformamide solvate and has a considerable number of very long carbon--carbon bonds. Three independent bonds have lengths of 1"597 (3), 1-597 (3) and 1"577 (3) A. The molecule forms two, strong hydrogen bonds (2.668 A) to related molecules of the dimethylformamide solvate and is possibly stabilized by these bonds. There are two molecules of symmetrical cedrone and four molecules of dimethylformamide in the unit cell. Crystal data: monoclinic P21/c, a=9-322 (3), b=8.250 (2), c= 15.804 (4) A, ,8= 101"86 (3)°, Z =2, Dx= 1.335 g.cm-s, Dm= 1"34 (1) http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry International Union of Crystallography

The crystal and molecular structure of symmetrical cedrone, a dimeric oxidation product of trimethylphloroglucinol

The crystal and molecular structure of symmetrical cedrone, a dimeric oxidation product of trimethylphloroglucinol


Abstract

<h2>Acta Crystallographica Section B</h2><h3>Structural Crystallography and Crystal Chemistry</h3><h3>0567-7408</h3> <h2>research papers</h2> Volume 28 Part 1 Pages 298-304 January 1972 <h2>The crystal and molecular structure of symmetrical cedrone, a dimeric oxidation product of trimethylphloroglucinol</h2> J. A. Beisler and J. V. Silverton Acta Cryst. (1972). B28, 298 The Crystal and Molecular Structure of Symmetrical Cedrone, a Dimeric Oxidation Product of Trimethylphloroglucinol BY J. A. BEISLER The National Institute of Arthritis and Metabolic Diseases AND J. V. SILVERTON The National Heart and Lung Institute, Bethesda, Maryland 20014, U.S.A. (Received 29 January 1971) Symmetrical cedrone, C1sH2006, obtained by dimerization of trimethylphloroglucinol has been shown to be a centrosymmetric pentacyclic structure in the crystal of its dimethylformamide solvate and has a considerable number of very long carbon--carbon bonds. Three independent bonds have lengths of 1"597 (3), 1-597 (3) and 1"577 (3) A. The molecule forms two, strong hydrogen bonds (2.668 A) to related molecules of the dimethylformamide solvate and is possibly stabilized by these bonds. There are two molecules of symmetrical cedrone and four molecules of dimethylformamide in the unit cell. Crystal data: monoclinic P21/c, a=9-322 (3), b=8.250 (2), c= 15.804 (4) A, ,8= 101"86 (3)°, Z =2, Dx= 1.335 g.cm-s, Dm= 1"34 (1)

Loading next page...
 
/lp/international-union-of-crystallography/the-crystal-and-molecular-structure-of-symmetrical-cedrone-a-dimeric-eIcgb24ZUh

References (0)

References for this paper are not available at this time. We will be adding them shortly, thank you for your patience.

Publisher
International Union of Crystallography
Copyright
Copyright (c) 1972 International Union of Crystallography
ISSN
0567-7408
DOI
10.1107/S0567740872002213
Publisher site
See Article on Publisher Site

Abstract

<h2>Acta Crystallographica Section B</h2><h3>Structural Crystallography and Crystal Chemistry</h3><h3>0567-7408</h3> <h2>research papers</h2> Volume 28 Part 1 Pages 298-304 January 1972 <h2>The crystal and molecular structure of symmetrical cedrone, a dimeric oxidation product of trimethylphloroglucinol</h2> J. A. Beisler and J. V. Silverton Acta Cryst. (1972). B28, 298 The Crystal and Molecular Structure of Symmetrical Cedrone, a Dimeric Oxidation Product of Trimethylphloroglucinol BY J. A. BEISLER The National Institute of Arthritis and Metabolic Diseases AND J. V. SILVERTON The National Heart and Lung Institute, Bethesda, Maryland 20014, U.S.A. (Received 29 January 1971) Symmetrical cedrone, C1sH2006, obtained by dimerization of trimethylphloroglucinol has been shown to be a centrosymmetric pentacyclic structure in the crystal of its dimethylformamide solvate and has a considerable number of very long carbon--carbon bonds. Three independent bonds have lengths of 1"597 (3), 1-597 (3) and 1"577 (3) A. The molecule forms two, strong hydrogen bonds (2.668 A) to related molecules of the dimethylformamide solvate and is possibly stabilized by these bonds. There are two molecules of symmetrical cedrone and four molecules of dimethylformamide in the unit cell. Crystal data: monoclinic P21/c, a=9-322 (3), b=8.250 (2), c= 15.804 (4) A, ,8= 101"86 (3)°, Z =2, Dx= 1.335 g.cm-s, Dm= 1"34 (1)

Journal

Acta Crystallographica Section B: Structural Crystallography and Crystal ChemistryInternational Union of Crystallography

Published: Jan 15, 1972

There are no references for this article.