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The anionic coordination polymer {K2PtII2AgI8(2,2'-bipyridine)2(O2CCF3)14}n

The trimetallic compound catena-polydipotassium(I) bis(2,2'-bipyridine)di-3-trifluoroacetato-dodeca-2-trifluoroacetato-diplatinum(II)octasilver(I), K2Pt2Ag8(C2F3O2)14(C10H8N2)2, forms an extended structure in the solid state. Electrostatic interactions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2- ligands. PtPt interactions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic interactions with K+ ions provide connectivity between adjacent polymeric structures. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography

The anionic coordination polymer {K2PtII2AgI8(2,2'-bipyridine)2(O2CCF3)14}n

Abstract

The trimetallic compound catena-polydipotassium(I) bis(2,2'-bipyridine)di-3-trifluoroacetato-dodeca-2-trifluoroacetato-diplatinum(II)octasilver(I), K2Pt2Ag8(C2F3O2)14(C10H8N2)2, forms an extended structure in the solid state. Electrostatic interactions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2- ligands. PtPt interactions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic interactions with K+ ions provide connectivity between adjacent polymeric structures.
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