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Tetra--benzoato-O:O'-bis(benzoato-O,O')(1,10-phenanthroline-N,N')lanthanum(III)

Tetra--benzoato-O:O'-bis(benzoato-O,O')(1,10-phenanthroline-N,N')lanthanum(III) The title complex, La2(C12H8N2)2(C6H5CO2)6, has a binuclear cage structure in which two La atoms are bridged by four benzoate ions with an LaLa distance of 4.1143 (3) A. The complex has a center of symmetry. The benzoate groups coordinate each LaIII atom in three different ways. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section E: Structure Reports Online International Union of Crystallography

Tetra--benzoato-O:O'-bis(benzoato-O,O')(1,10-phenanthroline-N,N')lanthanum(III)

Tetra--benzoato-O:O'-bis(benzoato-O,O')(1,10-phenanthroline-N,N')lanthanum(III)

Acta Crystallographica Section E: Structure Reports Online , Volume 57 (3): m122 – Feb 28, 2001

Abstract

The title complex, La2(C12H8N2)2(C6H5CO2)6, has a binuclear cage structure in which two La atoms are bridged by four benzoate ions with an LaLa distance of 4.1143 (3) A. The complex has a center of symmetry. The benzoate groups coordinate each LaIII atom in three different ways.

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References (1)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2001 International Union of Crystallography
ISSN
1600-5368
eISSN
1600-5368
DOI
10.1107/S1600536801002963
Publisher site
See Article on Publisher Site

Abstract

The title complex, La2(C12H8N2)2(C6H5CO2)6, has a binuclear cage structure in which two La atoms are bridged by four benzoate ions with an LaLa distance of 4.1143 (3) A. The complex has a center of symmetry. The benzoate groups coordinate each LaIII atom in three different ways.

Journal

Acta Crystallographica Section E: Structure Reports OnlineInternational Union of Crystallography

Published: Feb 28, 2001

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