Structures of one-dimensional PdII-PdIV mixed-valence complexes, PdIILPdIVCl2LY4 (Y= ClO4 and PF6), and their parent PdII and PdIV complexes, PdIIL(ClO4)2 and PdIVCl2L(NO3)2.HNO3.H2O, with 1,4,8,11-tetraazacyclotetradecane (L)
Abstract
<h2>Acta Crystallographica Section C</h2><h3>Crystal Structure Communications</h3><h3>0108-2701</h3> <h2>research papers (metal-organic compounds)</h2> Volume 42 Part 8 Pages 963-968 August 1986 <h2>Structures of one-dimensional Pd II -Pd IV mixed-valence complexes, [Pd II L ][Pd IV Cl 2 L ] Y 4 ( Y = ClO 4 and PF 6 ), and their parent Pd II and Pd IV complexes, [Pd II L ](ClO 4 ) 2 and [Pd IV Cl 2 L ](NO 3 ) 2 .HNO 3 .H 2 O, with 1,4,8,11-tetraazacyclotetradecane ( L )</h2> K. Toriumi, M. Yamashita, H. Ito and T. Ito Acta Cryst. (1986). C42, 963-968 Structures of One-Dimensional PdN-PdIv Mixed-Valence Complexes, [pdIIL][pdlvCI2L]Y4 (Y-- CIO4 and PF6), and Their Parent PdIx and PdIv Complexes, [pdnL](CIO4)2 and [pdzvCI2L](NO3)2.HNO3.H20, with 1,4,8,11-Tetraazacyclotetra- decane (L) BY KOSHIRO TORIUMa, I~ASAHIRO YAMASHITA, HARUKO ITO AND TASUKU ITO Department of Applied Molecular Science, Institute for Molecular Science, Okazaki National Research Institutes, Okazaki 444, Japan (Received 7 May 1984; accepted 24 February 1986) Abstract. Molecular and crystal structures of the title compounds, [pdnL](C104)2 (1), [pdlvC12L](NO3)2.- HNO3.H20 (2), [pdI~L][pd~vC12L](C104)4 (3), and [Pd"L][pdIvCI2L](PF6)4 (4), have been determined by single-crystal X-ray diffraction at room temperature, 2(MoKa)=0.71073/~. Crystal data are: for (1), C~0H24ClzN4OsPd, Mr = 505.65, orthorhombic, Pbnm, a