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Polybis2-5-(pyrimidin-2-yl)tetrazolatozinc(II)

Polybis2-5-(pyrimidin-2-yl)tetrazolatozinc(II) The title compound, Zn(C5H3N6)2n, has a neutral two-dimensional square grid-like network structure, in which the central ZnII atom is located on an inversion centre and coordinated by six N atoms from four 5-(pyrimidin-2-yl)tetrazolate ligands in a distorted octahedral geometry Zn-N = 2.114 (3)-2.193 (3) A and N-Zn-N = 77.78 (9)-102.22 (9)Degrees. The tetrazolate ligand adopts an N,N':N''-tridentate chelating-bridging coordination mode. This complex is isostructural with the iron(II), cobalt(II) and nickel(II) analogues. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section E: Structure Reports Online International Union of Crystallography

Polybis2-5-(pyrimidin-2-yl)tetrazolatozinc(II)

Polybis2-5-(pyrimidin-2-yl)tetrazolatozinc(II)

Acta Crystallographica Section E: Structure Reports Online , Volume 63 (9): m2423 – Aug 24, 2007

Abstract

The title compound, Zn(C5H3N6)2n, has a neutral two-dimensional square grid-like network structure, in which the central ZnII atom is located on an inversion centre and coordinated by six N atoms from four 5-(pyrimidin-2-yl)tetrazolate ligands in a distorted octahedral geometry Zn-N = 2.114 (3)-2.193 (3) A and N-Zn-N = 77.78 (9)-102.22 (9)Degrees. The tetrazolate ligand adopts an N,N':N''-tridentate chelating-bridging coordination mode. This complex is isostructural with the iron(II), cobalt(II) and nickel(II) analogues.

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References (1)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2007 International Union of Crystallography
ISSN
1600-5368
eISSN
1600-5368
DOI
10.1107/S1600536807041414
Publisher site
See Article on Publisher Site

Abstract

The title compound, Zn(C5H3N6)2n, has a neutral two-dimensional square grid-like network structure, in which the central ZnII atom is located on an inversion centre and coordinated by six N atoms from four 5-(pyrimidin-2-yl)tetrazolate ligands in a distorted octahedral geometry Zn-N = 2.114 (3)-2.193 (3) A and N-Zn-N = 77.78 (9)-102.22 (9)Degrees. The tetrazolate ligand adopts an N,N':N''-tridentate chelating-bridging coordination mode. This complex is isostructural with the iron(II), cobalt(II) and nickel(II) analogues.

Journal

Acta Crystallographica Section E: Structure Reports OnlineInternational Union of Crystallography

Published: Aug 24, 2007

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