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catena-Poly4-bromo-2-(2-pyridylmethyliminomethyl)phenolatozinc(II)--chloro

catena-Poly4-bromo-2-(2-pyridylmethyliminomethyl)phenolatozinc(II)--chloro The title complex, Zn(C13H10BrN2O)Cln, is a chloride-bridged polynuclear zinc(II) compound. Each ZnII ion is five-coordinated in a square-pyramidal configuration, with one O and two N atoms of one Schiff base and one bridging Cl atom defining the basal plane, and another bridging Cl atom occupying the apical position. The novelty of the compound lies in the bridging by chlorine of two square-pyramidal Zn atoms, so that the bridging atom is apical for one Zn ion and basal for the other. This structural arrangement has not been observed before. The linked moieties form polymeric zigzag chains running along the a axis. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section C: Crystal Structure Communications International Union of Crystallography

catena-Poly4-bromo-2-(2-pyridylmethyliminomethyl)phenolatozinc(II)--chloro

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catena-Poly4-bromo-2-(2-pyridylmethyliminomethyl)phenolatozinc(II)--chloro

You, Z.-L
Acta Crystallographica Section C: Crystal Structure Communications , Volume 61 (10): m456 – Sep 30, 2005

Abstract

The title complex, Zn(C13H10BrN2O)Cln, is a chloride-bridged polynuclear zinc(II) compound. Each ZnII ion is five-coordinated in a square-pyramidal configuration, with one O and two N atoms of one Schiff base and one bridging Cl atom defining the basal plane, and another bridging Cl atom occupying the apical position. The novelty of the compound lies in the bridging by chlorine of two square-pyramidal Zn atoms, so that the bridging atom is apical for one Zn ion and basal for the other. This structural arrangement has not been observed before. The linked moieties form polymeric zigzag chains running along the a axis.

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References (10)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 2005 International Union of Crystallography
ISSN
0108-2701
eISSN
1600-5759
DOI
10.1107/S010827010502932X
pmid
16210760
Publisher site
See Article on Publisher Site

Abstract

The title complex, Zn(C13H10BrN2O)Cln, is a chloride-bridged polynuclear zinc(II) compound. Each ZnII ion is five-coordinated in a square-pyramidal configuration, with one O and two N atoms of one Schiff base and one bridging Cl atom defining the basal plane, and another bridging Cl atom occupying the apical position. The novelty of the compound lies in the bridging by chlorine of two square-pyramidal Zn atoms, so that the bridging atom is apical for one Zn ion and basal for the other. This structural arrangement has not been observed before. The linked moieties form polymeric zigzag chains running along the a axis.

Journal

Acta Crystallographica Section C: Crystal Structure Communications – International Union of Crystallography

Published: Sep 30, 2005

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