Bis(2,2'-bipyridine-2N,N')chloridocobalt(II) perchlorate

Z Gao; F Li

doi:10.1107/S1600536809049034

Gao, Z; Li, F

Acta Crystallographica Section E: Structure Reports Online , Volume 65 (12): m1664 – Nov 25, 2009

Abstract

In the cation of the title compound, CoCl(C10H8N2)2ClO4, the CoII atom displays a distorted trigonal-bipyramidal coordination geometry. The two pyridine rings in each 2,2'-bipyridine ligand form dihedral angles of 10.75 (12) and 4.28 (13)Degrees. The crystal packing is stabilized by interionic C-HO hydrogen bonds, C-H interactions and aromatic - stacking interactions, with centroid-centroid distances of 3.616 (7) A.

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Bis(2,2'-bipyridine-2N,N')chloridocobalt(II) perchlorate

Bis(2,2'-bipyridine-2N,N')chloridocobalt(II) perchlorate