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R. Wang
Tribochemistry of Lubricants
- Publisher
- Emerald Publishing
- Copyright
- Copyright © 2008 Emerald Group Publishing Limited. All rights reserved.
- ISSN
- 0036-8792
- DOI
- 10.1108/00368790810881524
- Publisher site
- See Article on Publisher Site
Abstract
Purpose – The paper's aim is to study tribological performances of two 2‐mercaptobenzothiazole derivatives which are ashless and lacking in phosphorous as lubricating oil additives in HVIW H150 base oils. Design/methodology/approach – The two 2‐mercaptobenzothiazole derivatives were synthesized; their tribological performances were evaluated with a four‐ball machine, and the worn surface was analyzed with a X‐ray photoelectron spectroscopy (XPS). Findings – The two compounds possess good anti‐wear properties and excellent load‐carrying capacity. According to the XPS results, the additive reacted with counter‐face metal and generated a sulphur‐containing inorganic film consisting of FeS, FeS 2 and FeSO 4 , and a complex N‐containing resin polymer film. Research limitations/implications – Their antioxidant properties are not estimated, and their anti‐wear action mechanism need to be further explored. Practical implications – Two useful ashless AW lubricating oil additives were synthesized, and may be has potential as gas engine lubricating oil additives. Originality/value – This paper provides a study of some N, S‐containing heterocyclic compounds as lubricating oil additives.
Journal
Industrial Lubrication and Tribology – Emerald Publishing
Published: Jun 20, 2008
Keywords: Additives; Oils; Tribology