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Purpose – To discuss synthesis and evaluation of organo‐metallic chalcones as second‐order nonlinear optical (SONLO) materials. Design/methodology/approach – The new chalcones have been synthesised via Knovoenagel reactions of ferrocen carboxaldehyde with two active methylene compounds. Findings – The ferrocenyl chalcones prepared have shown bathochromic shift and thermal stability in polymeric film. On heating the dye films up to 80°C the extent of degradation reached up to 12 per cent and very small amount of degradation was observed at 43 and 60°C. Originality/value – The paper shows that these compounds have UV‐Vis bathochromic shift, enabling them to be used as SONLO materials in the blue domain as well as dyes.
Pigment & Resin Technology – Emerald Publishing
Published: Mar 21, 2008
Keywords: Thermal stability; Optical properties of materials; Organometallic compounds
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