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Mesoscopic transformation at initial corrosion stage of 20# steel in aqueous solution under gas–liquid two-phase stratified flow condition

Mesoscopic transformation at initial corrosion stage of 20# steel in aqueous solution under... This study aims to investigate the initial corrosion behavior in aqueous solution of 20# seamless steel under (CO2/aqueous solution) gas–liquid two-phase stratified flow conditions.Design/methodology/approachThe initial corrosion behavior was studied through the weight loss methods, scanning electron microscopy with energy-dispersive x-ray spectroscopy and x-ray diffraction.FindingsThe corrosion rate of 20# steel obviously increases with the increasing gas pressure at different corrosion time when the CO2 pressure is less than 0.11 MPa, and the increase of corrosion rate tends to be steady when the pressure exceeds 0.11 MPa. With the increase of CO2 pressure, the corrosion products changed from flocculent to acicular, granular and scaly. A four-stage model for the growth of the corrosion product layer was proposed, namely, the diffusion reaction stage, the local film formation stage, the complete film formation stage and the densification stage of the product film.Originality/valueA four-stage model for the growth of the corrosion product layer on the pipe wall surface under this condition was proposed, namely, the diffusion reaction stage, the local film formation stage, the complete film formation stage and the densification stage of the product film. The growing process and densification mechanism of corrosion products layer were discussed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Anti-Corrosion Methods and Materials Emerald Publishing

Mesoscopic transformation at initial corrosion stage of 20# steel in aqueous solution under gas–liquid two-phase stratified flow condition

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Publisher
Emerald Publishing
Copyright
© Emerald Publishing Limited
ISSN
0003-5599
DOI
10.1108/acmm-02-2020-2257
Publisher site
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Abstract

This study aims to investigate the initial corrosion behavior in aqueous solution of 20# seamless steel under (CO2/aqueous solution) gas–liquid two-phase stratified flow conditions.Design/methodology/approachThe initial corrosion behavior was studied through the weight loss methods, scanning electron microscopy with energy-dispersive x-ray spectroscopy and x-ray diffraction.FindingsThe corrosion rate of 20# steel obviously increases with the increasing gas pressure at different corrosion time when the CO2 pressure is less than 0.11 MPa, and the increase of corrosion rate tends to be steady when the pressure exceeds 0.11 MPa. With the increase of CO2 pressure, the corrosion products changed from flocculent to acicular, granular and scaly. A four-stage model for the growth of the corrosion product layer was proposed, namely, the diffusion reaction stage, the local film formation stage, the complete film formation stage and the densification stage of the product film.Originality/valueA four-stage model for the growth of the corrosion product layer on the pipe wall surface under this condition was proposed, namely, the diffusion reaction stage, the local film formation stage, the complete film formation stage and the densification stage of the product film. The growing process and densification mechanism of corrosion products layer were discussed.

Journal

Anti-Corrosion Methods and Materials – Emerald Publishing

Published: May 25, 2021

Keywords: CO2 corrosion; Stratified flow; Corrosion product layer growth model; Densification process

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