Urea-based flexible dicarboxylate linkers for three-dimensional metal-organic frameworks

Urea-based flexible dicarboxylate linkers for three-dimensional metal-organic frameworks Inorganica Chimica Acta 475 (2018) 35–46 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Urea-based flexible dicarboxylate linkers for three-dimensional metal-organic frameworks Sebastian Glomb, Gamall Makhloufi, Irina Gruber, Christoph Janiak Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, 40204 Düsseldorf, Germany article i nfo abstract Article history: The metal-organic frameworks (MOFs) 3D-[Mn (L1) (DMF)]2DMF (1), 3D-[Cd (L2) (DMF) ](3), 2 2 2 2 3 Received 30 June 2017 [Zn (L2) (DMF) ](4) and 3D-[Mn (L2) (DMF) ](5) are the first examples of three-dimensional metal- 2 2 3 2 2 3 Received in revised form 7 September 2017 organic networks constructed from a single ditopic dicarboxylate linker (i.e., without bridging co-ligands) Accepted 11 September 2017 2 0 2 0 with an urea group in the linker axis (L1 = 4,4 -(carbonylbis(azanediyl))dibenzoate; L2 = 4,4 - Available online 19 September 2017 2+ 2 (carbonylbis(azanediyl))bis(3-methylbenzoate), DMF = dimethylformamide). From Cd and L1 a1D coordination polymer 1D-[Cd(L1)(DMF) ](2) is formed. The urea group is engaged in hydrogen bonding Dedicated to Prof. Ionel Haiduc on the occasion of his 80th birthday. with the C(4)[R (6)] motif to an oxygen atom of a DMF solvent (in 1) or a metal-coordinated carboxylate group http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganica Chimica Acta Elsevier

Urea-based flexible dicarboxylate linkers for three-dimensional metal-organic frameworks

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0020-1693
eISSN
1873-3255
D.O.I.
10.1016/j.ica.2017.09.029
Publisher site
See Article on Publisher Site

Abstract

Inorganica Chimica Acta 475 (2018) 35–46 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Urea-based flexible dicarboxylate linkers for three-dimensional metal-organic frameworks Sebastian Glomb, Gamall Makhloufi, Irina Gruber, Christoph Janiak Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, 40204 Düsseldorf, Germany article i nfo abstract Article history: The metal-organic frameworks (MOFs) 3D-[Mn (L1) (DMF)]2DMF (1), 3D-[Cd (L2) (DMF) ](3), 2 2 2 2 3 Received 30 June 2017 [Zn (L2) (DMF) ](4) and 3D-[Mn (L2) (DMF) ](5) are the first examples of three-dimensional metal- 2 2 3 2 2 3 Received in revised form 7 September 2017 organic networks constructed from a single ditopic dicarboxylate linker (i.e., without bridging co-ligands) Accepted 11 September 2017 2 0 2 0 with an urea group in the linker axis (L1 = 4,4 -(carbonylbis(azanediyl))dibenzoate; L2 = 4,4 - Available online 19 September 2017 2+ 2 (carbonylbis(azanediyl))bis(3-methylbenzoate), DMF = dimethylformamide). From Cd and L1 a1D coordination polymer 1D-[Cd(L1)(DMF) ](2) is formed. The urea group is engaged in hydrogen bonding Dedicated to Prof. Ionel Haiduc on the occasion of his 80th birthday. with the C(4)[R (6)] motif to an oxygen atom of a DMF solvent (in 1) or a metal-coordinated carboxylate group

Journal

Inorganica Chimica ActaElsevier

Published: Apr 24, 2018

References

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