Colloids and Surfaces A 538 (2018) 155–163 Contents lists available at ScienceDirect Colloids and Surfaces A journal homepage: www.elsevier.com/locate/colsurfa Research paper Thin ﬁlms of an axially chiral bibenzo[c]phenanthrene diol and its enantiomers: Film structure, optical property, and photoelectrochemical response a,b a c a Md. Nazmul Kayes , Mohammad Shahabuddin , Md. Jalil Miah , Michinori Karikomi , a a a a, Sachio Yoshihara , Eri Nasuno , Norihiro Kato , Ken-ichi Iimura Graduate School of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya, Tochigi, 321-8585, Japan Department of Chemistry, University of Barisal, Barisal, 8200, Bangladesh Department of Mechanical and Chemical Engineering, Islamic University of Technology, Gazipur, Bangladesh GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: A helically distorted and polycondensed bisphenol [1,1′-bibenzo[c]phenanthrene]-2,2′-diol (HEBPOL) and its Axially chiral diol separated optically pure enantiomers were used to prepare thin ﬁlms and to explore their optoelectronic Thin ﬁlm properties. Due to both hydrophobic aromatic rings and hydrophilic −OH groups the compound possessed Enantiomer amphiphilic characters, which helps to form a stable layer at the air-water interface. The stable ﬁlm from the air- Photocurrent water interface was then transferred to diﬀerent types of solid substrates by Langmuir-Blodgett (LB) technique. Circular dichroism spectra In the
Colloids and Surfaces A: Physicochemical and Engineering Aspects – Elsevier
Published: Feb 5, 2018
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