J. Chem. Thermodynamics 121 (2018) 112–120 Contents lists available at ScienceDirect J. Chem. Thermodynamics journal homepage: www.elsevier.com/locate/jct Thermodynamic study of molecular interaction-selectivity in separation processes based on limiting activity coefﬁcients a,b,⇑ c c Urszula Doman´ ska , Monika Karpin´ ska , Michal Wlazło Industrial Chemistry Research Institute, Rydygiera 8, 01-793 Warsaw, Poland Thermodynamic Research Unit, School of Chemical Engineering, University of KwaZulu-Natal, Howard College Campus, King George V Avenue, Durban 4001, South Africa Department of Physical Chemistry, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Durban, Poland ar ti c l e i nf o ab stra ct Article history: The effect of interactions between organic solvents and water on the interfacial and bulk properties of Received 23 November 2017 N-ethyl-N-methylmorpholinium dicyanamide, [EMMor][DCA] were discussed on the base of the limiting Received in revised form 8 February 2018 1 1 activity coefﬁcients c values. The experimental c values were determined by gas–liquid chromatog- 13 13 Accepted 13 February 2018 raphy at temperatures from (298.15 to 368.15) K for 61 assorted solutes—among them, alkanes (linear, Available online 17 February 2018 branched, or cyclic), alkenes, alkynes, aromatic hydrocarbons, alcohols, water, thiophene, tetrahydrofu- ran, 1,4-dioxane, ethers, acetone, ketones, acetonitrile, pyridine,
The Journal of Chemical Thermodynamics – Elsevier
Published: Jun 1, 2018
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