Thermal behavior and decomposition of cerium(III) butanoate, pentanoate and hexanoate salts upon heating in argon

Thermal behavior and decomposition of cerium(III) butanoate, pentanoate and hexanoate salts upon... •The thermal decomposition of cerium butanoate, pentanoate and hexanoate has been studied in Ar.•All compounds present transitions including melting prior to decomposition.•Gas release in the molten state results in irregular mass loss.•CO2 and symmetrical ketones are the main evolving gas species.•Ce2O(CnH2n+1CO2)4 and Ce2O2CO3 intermediate are detected before CeO2 formation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Analytical and Applied Pyrolysis Elsevier

Thermal behavior and decomposition of cerium(III) butanoate, pentanoate and hexanoate salts upon heating in argon

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0165-2370
eISSN
1873-250X
D.O.I.
10.1016/j.jaap.2017.06.022
Publisher site
See Article on Publisher Site

Abstract

•The thermal decomposition of cerium butanoate, pentanoate and hexanoate has been studied in Ar.•All compounds present transitions including melting prior to decomposition.•Gas release in the molten state results in irregular mass loss.•CO2 and symmetrical ketones are the main evolving gas species.•Ce2O(CnH2n+1CO2)4 and Ce2O2CO3 intermediate are detected before CeO2 formation.

Journal

Journal of Analytical and Applied PyrolysisElsevier

Published: Jul 1, 2017

References

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