The Princess and the Pea Effect: Influence of the first layer on polyelectrolyte multilayer assembly and properties

The Princess and the Pea Effect: Influence of the first layer on polyelectrolyte multilayer... Journal of Colloid and Interface Science 502 (2017) 165–171 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Regular Article The Princess and the Pea Effect: Influence of the first layer on polyelectrolyte multilayer assembly and properties a a,b,⇑ Xuejian Lyu , Amy M. Peterson Department of Mechanical Engineering, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA 01609, United States Department of Chemical Engineering, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA 01609, United States graphical a bstract article i nfo abstract Article history: In many applications of polyelectrolyte multilayers (PEMs), a base polycation layer is adsorbed to pro- Received 8 February 2017 mote adhesion of the PEM to the substrate. In this report, the effect of the first polyelectrolyte adsorbed Revised 26 April 2017 in a PEM was investigated by assembling PEMs with first layer polycations of different chemistries and Accepted 27 April 2017 molecular weights. In this study, quartz crystal microbalance with dissipation monitoring (QCM-D) Available online 29 April 2017 was used to monitor the PEM assembly process. First layer choice affects the total mass accumulation of the PEM as well as the stoichiometry of the PEM, although linear growth was observed http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Colloid and Interface Science Elsevier

The Princess and the Pea Effect: Influence of the first layer on polyelectrolyte multilayer assembly and properties

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier Inc.
ISSN
0021-9797
eISSN
1095-7103
D.O.I.
10.1016/j.jcis.2017.04.091
Publisher site
See Article on Publisher Site

Abstract

Journal of Colloid and Interface Science 502 (2017) 165–171 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Regular Article The Princess and the Pea Effect: Influence of the first layer on polyelectrolyte multilayer assembly and properties a a,b,⇑ Xuejian Lyu , Amy M. Peterson Department of Mechanical Engineering, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA 01609, United States Department of Chemical Engineering, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA 01609, United States graphical a bstract article i nfo abstract Article history: In many applications of polyelectrolyte multilayers (PEMs), a base polycation layer is adsorbed to pro- Received 8 February 2017 mote adhesion of the PEM to the substrate. In this report, the effect of the first polyelectrolyte adsorbed Revised 26 April 2017 in a PEM was investigated by assembling PEMs with first layer polycations of different chemistries and Accepted 27 April 2017 molecular weights. In this study, quartz crystal microbalance with dissipation monitoring (QCM-D) Available online 29 April 2017 was used to monitor the PEM assembly process. First layer choice affects the total mass accumulation of the PEM as well as the stoichiometry of the PEM, although linear growth was observed

Journal

Journal of Colloid and Interface ScienceElsevier

Published: Sep 15, 2017

References

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