Journal of Analytical and Applied Pyrolysis 126 (2017) 323–331 Contents lists available at ScienceDirect Journal of Analytical and Applied Pyrolysis journal homepage: www.elsevier.com/locate/jaap The inﬂuence of alkaline cations on the mechanism and kinetics of MARK dehydration of polymeric phthalatocuprate(II) dihydrates a, b b c Jelena D. Zdravković , Dejan D. Poleti , Jelena R. Rogan , Vladimir A. Blagojević , d e Katalin Mészáros Szécsényi , Dragica M. Minić Innovation Centre − Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade, Serbia Institute of Technical Sciences SASA, Knez Mihailova 35/IV, 11000 Belgrade, Serbia Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovica 3, 21000 Novi Sad, Serbia Faculty of Physical Chemistry, University of Belgrade, Studentski trg 16, 11000 Belgrade, Serbia ARTICLE I NFO ABSTRACT Keywords: Thermal dehydration of two heterometallic complexes containing dianion of phthalic acid, pht, Na [Cu Heterometallic complexes (pht) ]· 2H O, 1, and K [Cu(pht) ]·2H O, 2, was investigated under non-isothermal conditions. Mechanism 2 2 2 2 2 Mechanism and kinetics of dehydration and kinetics of dehydration were analyzed in detail
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