The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates

The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric... •Degradation of two polymeric phthalatocuprate(II) dihydrates was studied using TG/DSC/MS measurements and XRPD analysis.•The reversibility of dehydration processes was identified using XRPD and TG/DSC analysis.•Detail analysis of dehydration kinetics was studied using isoconversional and non-isoconversional methods.•Thermodynamic and kinetic parameters for dehydration process have been determined.•The dehydrated complexes were investigated as possible candidates for H2 adsorption, using molecular simulations. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Analytical and Applied Pyrolysis Elsevier

The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0165-2370
eISSN
1873-250X
D.O.I.
10.1016/j.jaap.2017.05.014
Publisher site
See Article on Publisher Site

Abstract

•Degradation of two polymeric phthalatocuprate(II) dihydrates was studied using TG/DSC/MS measurements and XRPD analysis.•The reversibility of dehydration processes was identified using XRPD and TG/DSC analysis.•Detail analysis of dehydration kinetics was studied using isoconversional and non-isoconversional methods.•Thermodynamic and kinetic parameters for dehydration process have been determined.•The dehydrated complexes were investigated as possible candidates for H2 adsorption, using molecular simulations.

Journal

Journal of Analytical and Applied PyrolysisElsevier

Published: Jul 1, 2017

References

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